Mass spectrometric study of Ag/Se cluster ions and reaction of Ag and Se clusters | |
Xing, XP; Zhao, X; Zhang, X; Gao, Z | |
刊名 | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
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2002-03-01 | |
卷号 | 23期号:3页码:428-431 |
关键词 | Laser Ablation Time-of-flight Mass Spectrometer Clusters Reaction Ag/se Atom Clusters |
ISSN号 | 0251-0790 |
英文摘要 | The time-of-flight mass spectrometry was used to study Ag/Se cluster ions produced by laser ablation of solid samples, and a Laser Double Ablation Reactor was used to study the reaction of Ag and Se clusters. In Ag/Se binary cluster ions produced by laser ablation, [(Ag2Se)(n)Ag+], [(Ag2Se)(n)Ag-3(+)] are main compositions of positive cluster ions, while [(Ag2Se)(n)AgSe-], [(Ag2Se)(n)AgSe2-], [(Ag2Se)(n)Se-] are main compositions of negative cluster ions. The photolysis rates of positive cluster ions is higher than those of Ag/S clusters. During the laser double ablation experiment, the AgSen+ (n=4-9), AgSen- (n=4-7) were detected. In the series AgSe4+, the ions AgSe4+, AgSe6+ are comparatively abundant. It seems that the clustering mechanisms in the two processes are different. |
语种 | 英语 |
出版者 | HIGHER EDUCATION PRESS |
WOS记录号 | WOS:000175465700024 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/78195] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Gao, Z |
作者单位 | Chinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Xing, XP,Zhao, X,Zhang, X,et al. Mass spectrometric study of Ag/Se cluster ions and reaction of Ag and Se clusters[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2002,23(3):428-431. |
APA | Xing, XP,Zhao, X,Zhang, X,&Gao, Z.(2002).Mass spectrometric study of Ag/Se cluster ions and reaction of Ag and Se clusters.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,23(3),428-431. |
MLA | Xing, XP,et al."Mass spectrometric study of Ag/Se cluster ions and reaction of Ag and Se clusters".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 23.3(2002):428-431. |
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