Enantiomeric recognition of chiral 3,3-bridged-1,1 '-binaphthol dimer toward alpha-phenylethylamine and alpha-amino acid ester

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	Enantiomeric recognition of chiral 3,3-bridged-1,1 '-binaphthol dimer toward alpha-phenylethylamine and alpha-amino acid ester
	Liu, TJ; Chen, YJ; Zhang, KS; Wang, D; Guo, DW; Yang, XZ
刊名	CHIRALITY
	2001-10-01
卷号	13 期号:9 页码:595-600
关键词	Enantiomeric Recognition Alpha-phenylethyl Amine Alpha-amino Acid Ester Chiral 1 1 '-binaphthol-based Dimer
ISSN号	0899-0042
英文摘要	The 1,1'-binaphthol-based dimers with p-phenylenebis(2-ethynyl) spacer, (+)-6 and (+)-2, were synthesized as chiral host compounds. H-1 NMR, UV-vis, and fluorescent titration were used to evaluate the enantiomeric recognition abilities of the chiral host dimers toward the guest amine 7 and alpha -amino acid ester 8. The chiral BINOL-based dimers were found to have good enantiomeric recognition ability. The computer simulation of the host-guest complex molecules was carried out to describe the conformational changes of both naphthyl ring in the molecule of chiral host dimer after complexation with the guest molecule. Chirality 13:595-600, 2001. (C) 2001 Wiley-Liss, Inc.
语种	英语
出版者	WILEY-LISS
WOS记录号	WOS:000171403500013
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/77165]
专题	中国科学院化学研究所
通讯作者	Wang, D
作者单位	Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Polymer Phys Lab, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Liu, TJ,Chen, YJ,Zhang, KS,et al. Enantiomeric recognition of chiral 3,3-bridged-1,1 '-binaphthol dimer toward alpha-phenylethylamine and alpha-amino acid ester[J]. CHIRALITY,2001,13(9):595-600.
APA	Liu, TJ,Chen, YJ,Zhang, KS,Wang, D,Guo, DW,&Yang, XZ.(2001).Enantiomeric recognition of chiral 3,3-bridged-1,1 '-binaphthol dimer toward alpha-phenylethylamine and alpha-amino acid ester.CHIRALITY,13(9),595-600.
MLA	Liu, TJ,et al."Enantiomeric recognition of chiral 3,3-bridged-1,1 '-binaphthol dimer toward alpha-phenylethylamine and alpha-amino acid ester".CHIRALITY 13.9(2001):595-600.