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Preparation and catalytic properties of amphiphilic copolymer-stabilized platinum metals colloids
Tu, WX; Liu, HF; Liew, KY
刊名JOURNAL OF COLLOID AND INTERFACE SCIENCE
2000-09-15
卷号229期号:2页码:453-461
关键词Platinum Metals Colloid Amphiphilic Polymer Hydrogenation Catalyst
ISSN号0021-9797
英文摘要Several metal colloids stabilized by an amphiphilic copolymer, poly(1-vinylpyrrolidone-co-acrylic acid) (abbreviated as PVPAA), were prepared by refluxing alcohol-water mixed solutions of the corresponding metal precursors. They had small particle sizes and narrow size distributions. Their catalytic activity was tested by hydrogenation of cyclooctene, 1-dodecene, and ortho-chloronitrobenzene (o-CNB), With the introduction of nickel(II) ions to a PVPAA-stabilized platinum catalytic system, selective hydrogenation of o-CNB to ortho-chloroaniline (o-CAN) with 97.1% selectivity and 100% conversion was obtained. (C) 2000 Academic Press.
语种英语
出版者ACADEMIC PRESS INC
WOS记录号WOS:000089390500016
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/76521]  
专题中国科学院化学研究所
通讯作者Liu, HF
作者单位1.Chinese Acad Sci, Polymer Chem Lab, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, China Petrochem Corp, Beijing 100080, Peoples R China
3.Univ Sains Malaysia, Pusat Pengajiam Sains Kimia, Pulau Pinang 11800, Malaysia
推荐引用方式
GB/T 7714
Tu, WX,Liu, HF,Liew, KY. Preparation and catalytic properties of amphiphilic copolymer-stabilized platinum metals colloids[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE,2000,229(2):453-461.
APA Tu, WX,Liu, HF,&Liew, KY.(2000).Preparation and catalytic properties of amphiphilic copolymer-stabilized platinum metals colloids.JOURNAL OF COLLOID AND INTERFACE SCIENCE,229(2),453-461.
MLA Tu, WX,et al."Preparation and catalytic properties of amphiphilic copolymer-stabilized platinum metals colloids".JOURNAL OF COLLOID AND INTERFACE SCIENCE 229.2(2000):453-461.
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