A novel reaction: [60,70]fullerene reacting with 4,4,5,5-tetramethylimidazoline-2-thione and alpha-aminoacids as carbene reaction

CORC > 化学研究所 > 中国科学院化学研究所

	A novel reaction: [60,70]fullerene reacting with 4,4,5,5-tetramethylimidazoline-2-thione and alpha-aminoacids as carbene reaction
	Xu, JH ; Li, YL ; Guo, ZX ; Li, FY ; Shi, ZQ ; Pan, CY ; Zhu, DB
刊名	JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
	2000-07-01
卷号	61 期号:7 页码:1081-1088
关键词	Fullerene Carbene Reaction Cycloaddition
ISSN号	0022-3697
英文摘要	The results of characterization had shown that it was [1 + 2] cycloaddition reaction when [60,70]fullerene reacted with 4,4,5,5-terramethylidazoline-2-thione (1) and DL-valine by FT-IR, FD-mass, H-1 NMR, C-13 NMR, W-Vis spectra. [60] fullerene reacting with 4,4,5,5-tetramethylidazoline-2-thione (1) and other alpha-aminoacids such as L-leucine and alpha-aminoisobutyric acid had been also done in order to understand the reaction better, and the possible mechanism was put forward based on the results of characterization. In this reaction, reaction temperature was very important due to the reactivity of different ol-aminoacids and the result of the experiment had also shown that the reactivity of Dr-valine was more reactive than that of other two alpha-aminoacids. (C) 2000 Elsevier Science Ltd. All rights reserved.
语种	英语
出版者	PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号	WOS:000086950100015
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/76059]
专题	中国科学院化学研究所
通讯作者	Li, YL
作者单位	1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China 2.Univ Sci & Technol China, Dept Polymer & Engn, Hefei 230026, Peoples R China
推荐引用方式 GB/T 7714	Xu, JH,Li, YL,Guo, ZX,et al. A novel reaction: [60,70]fullerene reacting with 4,4,5,5-tetramethylimidazoline-2-thione and alpha-aminoacids as carbene reaction[J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS,2000,61(7):1081-1088.
APA	Xu, JH.,Li, YL.,Guo, ZX.,Li, FY.,Shi, ZQ.,...&Zhu, DB.(2000).A novel reaction: [60,70]fullerene reacting with 4,4,5,5-tetramethylimidazoline-2-thione and alpha-aminoacids as carbene reaction.JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS,61(7),1081-1088.
MLA	Xu, JH,et al."A novel reaction: [60,70]fullerene reacting with 4,4,5,5-tetramethylimidazoline-2-thione and alpha-aminoacids as carbene reaction".JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS 61.7(2000):1081-1088.