The study of intramolecular substitution reaction of polymer complex of cationic rhodium coordinated with polyallylmerrcaptan methynolacrylate

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	The study of intramolecular substitution reaction of polymer complex of cationic rhodium coordinated with polyallylmerrcaptan methynolacrylate
	Diao, KS ; Shi, XL ; Pan, PL ; Yuan, GQ ; Zhang, JC
刊名	ACTA POLYMERICA SINICA
	2000-12-01
期号	6 页码:711-714
关键词	Complex Square Planar Intramolecular Substitution
ISSN号	1000-3304
英文摘要	A new kind of cis-dicarbonyl rhodium complex,which contained S and O atoms as uncoordinated donors,has been synthesized. After studying its intramolecular substitution reaction through IR and XPS data,the result indicated that the weak S-->Rh and the weaker O-->Rh coordination bonds can replace the strong Rh-CR back donation bond to form tetradentated complex with the elevation of temperature and without the protection of CO. So the rhodium complex will not decompose for the drop of the terminal carbonyls and its stability is enhanced. The intramolecular substitution reaction is reversible. In the atmosphere of CO,the tetradentated complex will recover to bidentate complex with cis-dicarbonyl.
语种	英语
出版者	SCIENCE PRESS
WOS记录号	WOS:000165910900011
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/75631]
专题	中国科学院化学研究所
通讯作者	Diao, KS
作者单位	1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China 2.Beijing Univ Chem Technol, Dept Appl Chem, Beijing 100029, Peoples R China
推荐引用方式 GB/T 7714	Diao, KS,Shi, XL,Pan, PL,et al. The study of intramolecular substitution reaction of polymer complex of cationic rhodium coordinated with polyallylmerrcaptan methynolacrylate[J]. ACTA POLYMERICA SINICA,2000(6):711-714.
APA	Diao, KS,Shi, XL,Pan, PL,Yuan, GQ,&Zhang, JC.(2000).The study of intramolecular substitution reaction of polymer complex of cationic rhodium coordinated with polyallylmerrcaptan methynolacrylate.ACTA POLYMERICA SINICA(6),711-714.
MLA	Diao, KS,et al."The study of intramolecular substitution reaction of polymer complex of cationic rhodium coordinated with polyallylmerrcaptan methynolacrylate".ACTA POLYMERICA SINICA .6(2000):711-714.