The Measurement of the Ionization Potential and the Bond Energy Si(CH3)(2)Cl-2

doi:10.3866/PKU.WHXB19951002

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	The Measurement of the Ionization Potential and the Bond Energy Si(CH3)(2)Cl-2
	Shen Liusi 1; Qi Fei 1; Zhang Yunwu 1; Chen Wenwu 2; Wang Zhaohui 2; Ding Chuanfan 2; Kong Fanao 2
刊名	ACTA PHYSICO-CHIMICA SINICA
	1995
卷号	11 期号:10 页码:870-872
关键词	Si(Ch3)(2)Cl-2 Syrchrotron Radiation Photoionization Ionization Potential Chemical Bond Energy
ISSN号	1000-6818
DOI	10.3866/PKU.WHXB19951002
英文摘要	The vacuum ultraviolet photoionization spectrum of Si(CH3)(2)Cl-2 has been obtained with synchrotron radiation source. The adiabatic ionization potential of Si(CH3)(2)Cl-2 is 10.62 +/- 0.03eV (0.37eV lower than reported by PES), and the appearance potentials for Si(CH3)Cl-2(+), Si(CH3)(2)Cl+, SiCH3+ and SiCl+ are 11.25 +/- 0.03eV, 12.69 +/- 0.04eV, 15.1 +/- 0.1eV and 21.16eV +/- 0.1eV respectively. From these results, we estimate D(Si(CH3)Cl-2(+)-CH3)=0.63 +/- 0.03eV and D(Si(CH3)(2)Cl+-Cl))=2.07 +/- 0.04eV.
语种	英语
出版者	PEKING UNIV PRESS
WOS记录号	WOS:000207590900002
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/74029]
专题	中国科学院化学研究所
通讯作者	Shen Liusi
作者单位	1.Univ Sci & Technol China, Natl Lab Synchrotron Radiat, Hefei 230027, Peoples R China 2.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Shen Liusi,Qi Fei,Zhang Yunwu,et al. The Measurement of the Ionization Potential and the Bond Energy Si(CH3)(2)Cl-2[J]. ACTA PHYSICO-CHIMICA SINICA,1995,11(10):870-872.
APA	Shen Liusi.,Qi Fei.,Zhang Yunwu.,Chen Wenwu.,Wang Zhaohui.,...&Kong Fanao.(1995).The Measurement of the Ionization Potential and the Bond Energy Si(CH3)(2)Cl-2.ACTA PHYSICO-CHIMICA SINICA,11(10),870-872.
MLA	Shen Liusi,et al."The Measurement of the Ionization Potential and the Bond Energy Si(CH3)(2)Cl-2".ACTA PHYSICO-CHIMICA SINICA 11.10(1995):870-872.