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Rhodamine-based fluorescent sensor for mercury in buffer solution and living cells
Wang, Huan-Huan1,3; Xue, Lin1; Yu, Cai-Lan1; Qian, Yuan-Yu2; Jiang, Hua1
刊名DYES AND PIGMENTS
2011-12-01
卷号91期号:3页码:350-355
关键词Fluorescent Sensor Selectivity Mercury Rhodamine Cellular Imaging Ph Stable
ISSN号0143-7208
DOI10.1016/j.dyepig.2011.04.007
英文摘要A novel fluorescent sensor based on thiooxorhodamine B has been prepared to detect Hg2+ in aqueous buffer solution. It demonstrates high selectivity for sensing Hg2+ with about 383-fold enhancement in fluorescence emission intensity and micromolar sensitivity (K-d = 7.5 x 10(-6) mol L-1) in comparison with alkali and alkaline earth metal ions (K+, Na+, Mg2+, Ca2+) and other transition metal ions (Mn2+, Ni2+, Co2+, Cu2+, Zn2+, Cd2+, Ag+, Pb2+, Cr3+, Fe3+). Meanwhile the distinct color changes and rapid switch-on fluorescence also provide 'naked eyes' detection for Hg2+ over a broad pH range. Moreover, such sensor is cell-permeable and can visualize the changes of intracellular mercury ions in living cells using fluorescence microscopy. (C) 2011 Elsevier Ltd. All rights reserved.
语种英语
出版者ELSEVIER SCI LTD
WOS记录号WOS:000294528500012
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/73479]  
专题中国科学院化学研究所
通讯作者Jiang, Hua
作者单位1.Chinese Acad Sci, Inst Chem, CAS Key Lab Photochem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
2.Chinese Peoples Liberat Army Gen Hosp, Emergency Dept, Beijing 100853, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100190, Peoples R China
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GB/T 7714
Wang, Huan-Huan,Xue, Lin,Yu, Cai-Lan,et al. Rhodamine-based fluorescent sensor for mercury in buffer solution and living cells[J]. DYES AND PIGMENTS,2011,91(3):350-355.
APA Wang, Huan-Huan,Xue, Lin,Yu, Cai-Lan,Qian, Yuan-Yu,&Jiang, Hua.(2011).Rhodamine-based fluorescent sensor for mercury in buffer solution and living cells.DYES AND PIGMENTS,91(3),350-355.
MLA Wang, Huan-Huan,et al."Rhodamine-based fluorescent sensor for mercury in buffer solution and living cells".DYES AND PIGMENTS 91.3(2011):350-355.
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