Nanometer-Sized Reactor-A Porphyrin-Based Model System for Anion Species

doi:10.1002/chem.201100633

CORC > 化学研究所 > 中国科学院化学研究所

	Nanometer-Sized Reactor-A Porphyrin-Based Model System for Anion Species
	Li, Yong-jun 1; Zhao, Ying-jie 1; Flood, Amar H.2; Liu, Chao 1; Liu, Hui-biao 1; Li, Yu-liang 1
刊名	CHEMISTRY-A EUROPEAN JOURNAL
	2011-06-01
卷号	17 期号:27 页码:7499-7505
关键词	Anions Host-guest Systems Photosensitization Porphyrins Reactors
ISSN号	0947-6539
DOI	10.1002/chem.201100633
英文摘要	Although many cagelike molecules can create a catalytic environment for promoting chemical reactions, the construction of receptors that can host anionic species and sensitize their reaction is novel. Here we report the photochemically induced dimerization of the anion radicals of TCNQ (7,7,8,8-tetracyano-para-quinodimethane) in organic solvent under aerobic conditions when they are encapsulated inside a cationic photoactive receptor. There is clear evidence for a rate increase of over two orders of magnitude, photosensitization of the host, and demonstrated turnover of the catalyst.
语种	英语
出版者	WILEY-BLACKWELL
WOS记录号	WOS:000292211300017
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/73325]
专题	中国科学院化学研究所
通讯作者	Li, Yong-jun
作者单位	1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Indiana Univ, Dept Chem, Bloomington, IN 47405 USA
推荐引用方式 GB/T 7714	Li, Yong-jun,Zhao, Ying-jie,Flood, Amar H.,et al. Nanometer-Sized Reactor-A Porphyrin-Based Model System for Anion Species[J]. CHEMISTRY-A EUROPEAN JOURNAL,2011,17(27):7499-7505.
APA	Li, Yong-jun,Zhao, Ying-jie,Flood, Amar H.,Liu, Chao,Liu, Hui-biao,&Li, Yu-liang.(2011).Nanometer-Sized Reactor-A Porphyrin-Based Model System for Anion Species.CHEMISTRY-A EUROPEAN JOURNAL,17(27),7499-7505.
MLA	Li, Yong-jun,et al."Nanometer-Sized Reactor-A Porphyrin-Based Model System for Anion Species".CHEMISTRY-A EUROPEAN JOURNAL 17.27(2011):7499-7505.