The uptake of 2-methyl-3-buten-2-ol into aqueous mixed solutions of sulfuric acid and hydrogen peroxide | |
Liu, Ze; Ge, Maofa; Wang, Weigang; Yin, Shi; Tong, Shengrui | |
刊名 | PHYSICAL CHEMISTRY CHEMICAL PHYSICS
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2011 | |
卷号 | 13期号:6页码:2069-2075 |
ISSN号 | 1463-9076 |
DOI | 10.1039/c0cp00905a |
英文摘要 | Multiphase acid-catalyzed oxidation with hydrogen peroxide (H2O2) has been suggested recently to be a potential route to SOA formation from isoprene and its gas-phase oxidation products, the kinetics and chemical mechanism of this process have not been well-known yet. In this work, the uptake of 2-methyl-3-buten-2-ol (MBO), an important biogenic hydrocarbon and structurally similar to isoprene, into aqueous mixed solutions of H2O2 and sulfuric acid (H2SO4) was performed using a rotated wetted-wall reactor coupled to a differentially pumped single-photon ionization time of flight mass spectrometer (RWW-SPI-TOFMS). The reactive uptake coefficients (g) were acquired for the first time and the reaction pathways were deduced according to products information. The reactive uptake coefficients of MBO into H2SO4-H2O2 mixed solutions are much greater than that into H2SO4 solutions. Acetaldehyde, acetone and an on-line product, which transformed to isoprene readily in the duration of an off-line experiment, were suggested as products in this process. The further reactions of the carbonyl products can occur in acidic solution, which may play a role in SOA formation. Additionally, in real atmosphere the on-line product is apt to transform to isoprene, an acknowledged precursor of biogenic SOA. Thus, the multiphase acid-catalyzed oxidation of MBO with H2O2 might be a potential contributor to SOA loading. |
语种 | 英语 |
出版者 | ROYAL SOC CHEMISTRY |
WOS记录号 | WOS:000286628200016 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/73215] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Ge, Maofa |
作者单位 | Chinese Acad Sci, Beijing Natl Lab Mol Sci, State Key Lab Struct Chem Unstable & Stable Speci, Inst Chem, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, Ze,Ge, Maofa,Wang, Weigang,et al. The uptake of 2-methyl-3-buten-2-ol into aqueous mixed solutions of sulfuric acid and hydrogen peroxide[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2011,13(6):2069-2075. |
APA | Liu, Ze,Ge, Maofa,Wang, Weigang,Yin, Shi,&Tong, Shengrui.(2011).The uptake of 2-methyl-3-buten-2-ol into aqueous mixed solutions of sulfuric acid and hydrogen peroxide.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,13(6),2069-2075. |
MLA | Liu, Ze,et al."The uptake of 2-methyl-3-buten-2-ol into aqueous mixed solutions of sulfuric acid and hydrogen peroxide".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 13.6(2011):2069-2075. |
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