Self-Templating of Metal-Driven Supramolecular Self-Assembly: A General Approach toward 1D Inorganic Nanotubes

doi:10.1021/cm102649y

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	Self-Templating of Metal-Driven Supramolecular Self-Assembly: A General Approach toward 1D Inorganic Nanotubes
	Qiao, Yan; Wang, Yijie; Yang, Zhiyi; Lin, Yiyang; Huang, Jianbin
刊名	CHEMISTRY OF MATERIALS
	2011-03-08
卷号	23 期号:5 页码:1182-1187
关键词	Nanomaterials Self-assembly And Self-assembled Materials Semiconductors
ISSN号	0897-4756
DOI	10.1021/cm102649y
英文摘要	The rational design of one-dimensional (1D) inorganic nanomaterials directed by self-assembled soft matters is one of the most attractive subjects in modern chemistry. In this work, the self-templating approach based on metal cholate supramolecular self-assemblies is reported, which is distinct from the traditional soft template method. Under the framework of self-templating, metal ions can serve as both the inorganic precursor and constituent of the template; additional precursors which may change the solution conditions and interfere with the soft templates are not needed. It is demonstrated that self-templating method is a general approach to synthesize a series of ID inorganic nanotubes including ZnS, CuS, NiS, CdS, CoS, ZnSe, and ZnTe nanotubes. Moreover, the structural diversity and dynamic nature of organic architectures allow the preparation of size and shape-adjustable ID nanotubes through conveniently temporal and thermal controls. A possible mechanism for nanotube formation is also proposed.
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000287767200016
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/73119]
专题	中国科学院化学研究所
通讯作者	Huang, Jianbin
作者单位	Peking Univ, Coll Chem & Mol Engn, State Key Lab Struct Chem Unstable & Stable Speci, BNLMS, Beijing 100871, Peoples R China
推荐引用方式 GB/T 7714	Qiao, Yan,Wang, Yijie,Yang, Zhiyi,et al. Self-Templating of Metal-Driven Supramolecular Self-Assembly: A General Approach toward 1D Inorganic Nanotubes[J]. CHEMISTRY OF MATERIALS,2011,23(5):1182-1187.
APA	Qiao, Yan,Wang, Yijie,Yang, Zhiyi,Lin, Yiyang,&Huang, Jianbin.(2011).Self-Templating of Metal-Driven Supramolecular Self-Assembly: A General Approach toward 1D Inorganic Nanotubes.CHEMISTRY OF MATERIALS,23(5),1182-1187.
MLA	Qiao, Yan,et al."Self-Templating of Metal-Driven Supramolecular Self-Assembly: A General Approach toward 1D Inorganic Nanotubes".CHEMISTRY OF MATERIALS 23.5(2011):1182-1187.