Synthesis, Structure and Mimic Catalytic Activity of Novel Vanadium Haloperoxidase Model Complexes

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	Synthesis, Structure and Mimic Catalytic Activity of Novel Vanadium Haloperoxidase Model Complexes
	Cao Yun-Zhu 1; Li Zhang-Peng 1; Xing Yong-Heng 1; Wei Dong-Ming 1; Pu Zhi-Feng 2; Ge Mao-Fa 2; Shi Zhan 3
刊名	CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
	2011-05-10
卷号	32 期号:5 页码:1025-1032
关键词	Haloperoxidase Mimic Catalytic Activity Poly(Pyrazolyl) Borate Oxovanadium(Iv) Complex Crystal Structure
ISSN号	0251-0790
英文摘要	In order to mimic the active center of the V-HPOs, we designed and synthesized a series of oxovanadium complexes containing poly (pyrazolyl) borate ligands: VO(HB(3,5-Me(2)pz)(3)) (3,5-Me(2)pz) (HOOC-CH2CH2COO) (1) and VO(HB(3,5-Me(2)pz)(3)) (3,5-Me(2)pz) (C5H4N-COO) (2), which were characterized by X-ray single crystal diffraction. Based on the characteristics that vanadium(V) complexes catalyze phenol red oxidation of bromide into bromophenol blue in a water system under weak-acid condition, the study on catalytic activity about scorpionate oxovanadium(IV) complexes was preformed. The result shows that the scorpionate oxovanadium(IV) complexes exhibit catalytic activity to the extent under the similar conditions. The mechanism of the catalytic reaction was analyzed by molecular orbital theory.
语种	英语
出版者	HIGHER EDUCATION PRESS
WOS记录号	WOS:000291175800008
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/72171]
专题	中国科学院化学研究所
通讯作者	Xing Yong-Heng
作者单位	1.Liaoning Normal Univ, Coll Chem & Chem Engn, Dalian 116029, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China 3.Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
推荐引用方式 GB/T 7714	Cao Yun-Zhu,Li Zhang-Peng,Xing Yong-Heng,et al. Synthesis, Structure and Mimic Catalytic Activity of Novel Vanadium Haloperoxidase Model Complexes[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2011,32(5):1025-1032.
APA	Cao Yun-Zhu.,Li Zhang-Peng.,Xing Yong-Heng.,Wei Dong-Ming.,Pu Zhi-Feng.,...&Shi Zhan.(2011).Synthesis, Structure and Mimic Catalytic Activity of Novel Vanadium Haloperoxidase Model Complexes.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,32(5),1025-1032.
MLA	Cao Yun-Zhu,et al."Synthesis, Structure and Mimic Catalytic Activity of Novel Vanadium Haloperoxidase Model Complexes".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 32.5(2011):1025-1032.