A highly efficient Co (0) catalyst derived from metal-organic framework for the hydrolysis of ammonia borane

doi:10.1016/j.ijhydene.2011.05.120

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	A highly efficient Co (0) catalyst derived from metal-organic framework for the hydrolysis of ammonia borane
	Song, Ping; Li, Yaoqi; Li, Wei; He, Bei; Yang, Junzhi; Li, Xingguo
刊名	INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
	2011-08-01
卷号	36 期号:17 页码:10468-10473
关键词	Metal-organic Frameworks Heterogeneous Catalyst Ammonia Borane Hydrolysis
ISSN号	0360-3199
DOI	10.1016/j.ijhydene.2011.05.120
英文摘要	A Co (0) catalyst is synthesized by the reduction of a metal-organic framework (MOF) precursor Co(2)(bdc)(2)(dabco) (bdc = 1,4-benzenedicarboxylate; dabco = 1,4-diazabicyclo[2.2.2] octane). The amorphous catalyst exhibits highly efficient activity in the hydrolysis of ammonia borane (AB). The dehydrogenation of a 0.32 M aqueous AB solution completes in 1.4 min under room temperature. The porous structure in the MOF is proposed to play a key role. The catalytic effective Co (0) sites are stabilized by the organic molecules, which used to coordinate to Co (II) in the MOP precursor. This work implies that MOFs, with their large surface area and ample pore structures, may serve as ideal precursors for highly efficient heterogeneous catalysts. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
语种	英语
出版者	PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号	WOS:000295235200003
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/71929]
专题	中国科学院化学研究所
通讯作者	Li, Xingguo
作者单位	Peking Univ, BNLMS, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
推荐引用方式 GB/T 7714	Song, Ping,Li, Yaoqi,Li, Wei,et al. A highly efficient Co (0) catalyst derived from metal-organic framework for the hydrolysis of ammonia borane[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2011,36(17):10468-10473.
APA	Song, Ping,Li, Yaoqi,Li, Wei,He, Bei,Yang, Junzhi,&Li, Xingguo.(2011).A highly efficient Co (0) catalyst derived from metal-organic framework for the hydrolysis of ammonia borane.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,36(17),10468-10473.
MLA	Song, Ping,et al."A highly efficient Co (0) catalyst derived from metal-organic framework for the hydrolysis of ammonia borane".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 36.17(2011):10468-10473.