Consistency in the Sum Frequency Generation Intensity and Phase Vibrational Spectra of the Air/Neat Water Interface

doi:10.1021/jp110404h

CORC > 化学研究所 > 中国科学院化学研究所

	Consistency in the Sum Frequency Generation Intensity and Phase Vibrational Spectra of the Air/Neat Water Interface
	Feng, Ran-ran 2; Guo, Yuan 2; Lue, Rong 3; Velarde, Luis 1; Wang, Hong-fei 1
刊名	JOURNAL OF PHYSICAL CHEMISTRY A
	2011-06-16
卷号	115 期号:23 页码:6015-6027
ISSN号	1089-5639
DOI	10.1021/jp110404h
英文摘要	Substantial progress has been made in the quantitative understanding and interpretation of the hydrogen bonding and ordering structure of the air/water interface since the first sum-frequency generation vibrational spectroscopy (SFG-VS) measurement by Q. Du et al. in 1993 (Phys. Rev. Lett 1993, 70, 2312-2316). However, there are still disagreements and controversies on the consistency between the different experimental measurements, as well as in the theoretical and computational results. One critical problem lies in the lack of consistency between the SFG-VS intensity measurements and the recently developed SFG-VS phase spectra measurements of the neat air/water interface, which has inspired various theoretical efforts. In this report, the reliability of the SFG-VS intensity spectra of the air/neat water interface is to be quantitatively examined, and possible sources of inaccuracies in the SFG-VS phase spectral measurement are to be discussed based on the nonresonant SHG phase measurements. Solid evidence is shown indicating that the SFG-VS intensity spectra from different laboratories are now quantitatively converging and in agreement with each other. However, the possible inaccuracies and inconsistencies in the SFG-VS phase spectra measurements need to be carefully examined against a properly corrected phase standard to take full advantage of this powerful experimental tool.
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000291338800034
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/71283]
专题	中国科学院化学研究所
通讯作者	Wang, Hong-fei
作者单位	1.Pacific NW Natl Lab, William R Wiley Environm Mol Sci Lab, Richland, WA 99352 USA 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China 3.Renmin Univ China, Dept Chem, Beijing 100872, Peoples R China
推荐引用方式 GB/T 7714	Feng, Ran-ran,Guo, Yuan,Lue, Rong,et al. Consistency in the Sum Frequency Generation Intensity and Phase Vibrational Spectra of the Air/Neat Water Interface[J]. JOURNAL OF PHYSICAL CHEMISTRY A,2011,115(23):6015-6027.
APA	Feng, Ran-ran,Guo, Yuan,Lue, Rong,Velarde, Luis,&Wang, Hong-fei.(2011).Consistency in the Sum Frequency Generation Intensity and Phase Vibrational Spectra of the Air/Neat Water Interface.JOURNAL OF PHYSICAL CHEMISTRY A,115(23),6015-6027.
MLA	Feng, Ran-ran,et al."Consistency in the Sum Frequency Generation Intensity and Phase Vibrational Spectra of the Air/Neat Water Interface".JOURNAL OF PHYSICAL CHEMISTRY A 115.23(2011):6015-6027.