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Structure and Properties of High Melt Strength Polypropylene Prepared by Combined Method of Blending and Crosslinking
An, Yanjie1,2; Zhang, Zhenjiang1,2; Wang, Yanhui1; Qiu, Jian1; Tang, Tao1
刊名JOURNAL OF APPLIED POLYMER SCIENCE
2010-05-05
卷号116期号:3页码:1739-1746
关键词Blending Crosslinking Melt Polypropylene (Pp) Strength
ISSN号0021-8995
DOI10.1002/app.31610
英文摘要High melt strength polypropylene (HMSPP) was prepared by in situ heat induction reaction, in which pure polypropylene (PP) powders without any additives was used as basic resin, and low density polyethylene (LDPE) and trimethylolpropane triacrylate (TMPTA) were added as blending resin and as cross-linking agent, respectively. Microstructure of the obtained HMSPP (PP/LDPE/TMPTA blends) was characterized by FTIR, Wide-angle X-ray diffraction (WARD), and testing of gel content. The effect of LDPE content on melt strength and melt flow rate of HMSPP were investigated. When the content of LDPE was 40 wt %, the melt strength of the HMSPP was above 16 CN, which was much higher than those of pure PP powder (2.6 CN) and PP/LDPE blends without TMPTA (6.1 CN). Moreover, thermal behavior and mechanical properties of the HMSPP were also investigated. The results showed that the thermal stability and impact strength of HMSPP were greatly improved. In addition, HMSPP possessed good processing performance and good foaming properties. The foams produced by HMSPP showed uniform, closed, and independent cells. (C) 2010 Wiley Periodicals, Inc. J Appl Polym Sci 116: 1739-1746, 2010
语种英语
出版者JOHN WILEY & SONS INC
WOS记录号WOS:000275342200065
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/70673]  
专题中国科学院化学研究所
通讯作者Tang, Tao
作者单位1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
An, Yanjie,Zhang, Zhenjiang,Wang, Yanhui,et al. Structure and Properties of High Melt Strength Polypropylene Prepared by Combined Method of Blending and Crosslinking[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2010,116(3):1739-1746.
APA An, Yanjie,Zhang, Zhenjiang,Wang, Yanhui,Qiu, Jian,&Tang, Tao.(2010).Structure and Properties of High Melt Strength Polypropylene Prepared by Combined Method of Blending and Crosslinking.JOURNAL OF APPLIED POLYMER SCIENCE,116(3),1739-1746.
MLA An, Yanjie,et al."Structure and Properties of High Melt Strength Polypropylene Prepared by Combined Method of Blending and Crosslinking".JOURNAL OF APPLIED POLYMER SCIENCE 116.3(2010):1739-1746.
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