Chiral pyrrolidine-azole conjugates: Simple and efficient asymmetric organocatalysts for Michael addition to nitrostyrenes | |
Zhang Long2,3; Xu Hui1; Mi XueLing2,3; Luo SanZhong1; Cheng Jin-Pei1,2,3 | |
刊名 | CHINESE SCIENCE BULLETIN
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2010-06-01 | |
卷号 | 55期号:17页码:1735-1741 |
关键词 | Pyrrolidine Azole Organocatalysis Michael Addition Nitrostyrene |
ISSN号 | 1001-6538 |
DOI | 10.1007/s11434-010-3120-9 |
英文摘要 | Simple pyrrolidine-azole conjugates have been synthesized and found to be efficient catalysts for asymmetric Michael addition to nitrostyrenes. The identified optimal catalysts, pyrrolidine-azoles 2, 8 and 13, could catalyze the asymmetric Michael addition of a range of Michael donors and nitrostyrenes in high yields (up to 99%) and excellent stereoselectivities (up to 99: 1 dr and 97% ee). |
语种 | 英语 |
出版者 | SCIENCE PRESS |
WOS记录号 | WOS:000278900800007 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/70129] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Luo SanZhong |
作者单位 | 1.Chinese Acad Sci, BNLMS, CAS Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China 2.Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China 3.Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang Long,Xu Hui,Mi XueLing,et al. Chiral pyrrolidine-azole conjugates: Simple and efficient asymmetric organocatalysts for Michael addition to nitrostyrenes[J]. CHINESE SCIENCE BULLETIN,2010,55(17):1735-1741. |
APA | Zhang Long,Xu Hui,Mi XueLing,Luo SanZhong,&Cheng Jin-Pei.(2010).Chiral pyrrolidine-azole conjugates: Simple and efficient asymmetric organocatalysts for Michael addition to nitrostyrenes.CHINESE SCIENCE BULLETIN,55(17),1735-1741. |
MLA | Zhang Long,et al."Chiral pyrrolidine-azole conjugates: Simple and efficient asymmetric organocatalysts for Michael addition to nitrostyrenes".CHINESE SCIENCE BULLETIN 55.17(2010):1735-1741. |
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