Heterogeneous crystallization of hard spheres on patterned substrates | |
Xu, Wen-Sheng; Sun, Zhao-Yan; An, Li-Jia | |
刊名 | JOURNAL OF CHEMICAL PHYSICS
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2010-04-14 | |
卷号 | 132期号:14 |
关键词 | Crystal Structure Crystallisation Stacking Faults |
ISSN号 | 0021-9606 |
DOI | 10.1063/1.3383239 |
英文摘要 | We report a numerical investigation of the crystallization of monodisperse hard spheres on different patterned substrates. We find that the duration of a metastable fluid state, which may last for relatively long time in the homogeneous crystallization, can be deeply reduced or almost eliminated when a substrate is used as the seed of crystallization. In the presence of the square patterned substrate, which has the basic character of the body-centered cubic (bcc) crystal structure, a transient bcc crystal phase was observed, suggesting that the bcc structure could be possible to be stabilized by the square patterned substrates. The process of crystallization becomes complicated when the patterned substrate is incommensurate with the bulk crystal. Furthermore, a purely face-centered cubic or hexagonal close packed crystal phase with stacking faults can be generated by using a certain patterned substrate without other factors such as gravity. |
语种 | 英语 |
出版者 | AMER INST PHYSICS |
WOS记录号 | WOS:000276973500024 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/69583] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Sun, Zhao-Yan |
作者单位 | Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
推荐引用方式 GB/T 7714 | Xu, Wen-Sheng,Sun, Zhao-Yan,An, Li-Jia. Heterogeneous crystallization of hard spheres on patterned substrates[J]. JOURNAL OF CHEMICAL PHYSICS,2010,132(14). |
APA | Xu, Wen-Sheng,Sun, Zhao-Yan,&An, Li-Jia.(2010).Heterogeneous crystallization of hard spheres on patterned substrates.JOURNAL OF CHEMICAL PHYSICS,132(14). |
MLA | Xu, Wen-Sheng,et al."Heterogeneous crystallization of hard spheres on patterned substrates".JOURNAL OF CHEMICAL PHYSICS 132.14(2010). |
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