Fullerene Band-Like Assembly Induced by a Donor-pi-Acceptor Molecular Template on Au(111) Electrode Surface

doi:10.3866/PKU.WHXB20100704

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	Fullerene Band-Like Assembly Induced by a Donor-pi-Acceptor Molecular Template on Au(111) Electrode Surface
	Yan Hui-Juan; Wang Dong; Wen Guo-Yong; Zhang De-Qing; Wan Li-Jun
刊名	ACTA PHYSICO-CHIMICA SINICA
	2010-07-01
卷号	26 期号:7 页码:1893-1897
关键词	Self-assembly Fullerene Donor-pi-acceptor Scanning Tunneling Microscopy Band-like Assembly
ISSN号	1000-6818
DOI	10.3866/PKU.WHXB20100704
英文摘要	Fullerene has been extensively used in functional devices requiring electron transfer between fullerene and functional molecules. The investigation of multi. component assembly structures of fullerene and functional molecules on electrode surfaces will benefit the fabrication of fullerene based nanodevices as well as the study of their fundamental physical and chemical properties. The two dimensional (2D) self. assembly structure of C-60 and the donor-pi-acceptor molecule Z-beta-5-hexadecyloxy-1,3,3-trimethyl-2-indolium)-alpha-cyano-4-styryldicyanomethanide (C16H33O- I3CNQ) on an Au(111) electrode surface was investigated by electrochemical scanning tunneling microscopy (ECSTM) in HClO4. The C16H33O-I3CNQ molecules self. organized into a short. ranged ordered structure on the Au(111) surface. C-60 molecules formed band. like assembly structures templated by the C16H33O-I3CNQ adlayer. The orientation of the C60 band structure is controlled by the arrangement of the donor-pi-acceptor moieties. pi-pi stacking interactions and charge transfer between C-60 and C16H33O-I3CNQ may contribute to the formation of the C-60 band. like assembly. The results reported here are expected to provide a new approach for the fabrication of fullerene films and functional devices.
语种	英语
出版者	PEKING UNIV PRESS
WOS记录号	WOS:000279776400024
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/69437]
专题	中国科学院化学研究所
通讯作者	Zhang De-Qing
作者单位	Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, CAS Key Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Yan Hui-Juan,Wang Dong,Wen Guo-Yong,et al. Fullerene Band-Like Assembly Induced by a Donor-pi-Acceptor Molecular Template on Au(111) Electrode Surface[J]. ACTA PHYSICO-CHIMICA SINICA,2010,26(7):1893-1897.
APA	Yan Hui-Juan,Wang Dong,Wen Guo-Yong,Zhang De-Qing,&Wan Li-Jun.(2010).Fullerene Band-Like Assembly Induced by a Donor-pi-Acceptor Molecular Template on Au(111) Electrode Surface.ACTA PHYSICO-CHIMICA SINICA,26(7),1893-1897.
MLA	Yan Hui-Juan,et al."Fullerene Band-Like Assembly Induced by a Donor-pi-Acceptor Molecular Template on Au(111) Electrode Surface".ACTA PHYSICO-CHIMICA SINICA 26.7(2010):1893-1897.