Diastereoselective addition of lithium enolate of gamma-substituted alpha-diazoacetoacetate to N-sulfinyl imines

doi:10.1007/s11434-010-3140-5

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	Diastereoselective addition of lithium enolate of gamma-substituted alpha-diazoacetoacetate to N-sulfinyl imines
	Mo FanYang ; Li Fei ; Wang JianBo 1
刊名	CHINESE SCIENCE BULLETIN
	2010-09-01
卷号	55 期号:25 页码:2847-2854
关键词	Diazo Compound Pyrrolidine N-sulfinyl Imine Rhodium Diastereoselective Addition
ISSN号	1001-6538
DOI	10.1007/s11434-010-3140-5
英文摘要	Highly diastereoselective addition of lithium enolate of gamma-substituted alpha-diazoacetoacetate to chiral N-sulfinyl imines has been developed. The addition products were further subjected to photo-induced Wolff rearrangement or Rh(II)-catalyzed intramolecular N-H insertion to afford chiral 4,5-disubstituted 2-oxo and 3-oxo pyrrolidines, respectively.
语种	英语
出版者	SCIENCE PRESS
WOS记录号	WOS:000281695100017
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/69017]
专题	中国科学院化学研究所
通讯作者	Wang JianBo
作者单位	1.Peking Univ, BNLMS, Beijing 100871, Peoples R China 2.Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, Coll Chem, Beijing 100871, Peoples R China
推荐引用方式 GB/T 7714	Mo FanYang,Li Fei,Wang JianBo. Diastereoselective addition of lithium enolate of gamma-substituted alpha-diazoacetoacetate to N-sulfinyl imines[J]. CHINESE SCIENCE BULLETIN,2010,55(25):2847-2854.
APA	Mo FanYang,Li Fei,&Wang JianBo.(2010).Diastereoselective addition of lithium enolate of gamma-substituted alpha-diazoacetoacetate to N-sulfinyl imines.CHINESE SCIENCE BULLETIN,55(25),2847-2854.
MLA	Mo FanYang,et al."Diastereoselective addition of lithium enolate of gamma-substituted alpha-diazoacetoacetate to N-sulfinyl imines".CHINESE SCIENCE BULLETIN 55.25(2010):2847-2854.