Pyrene acetylide nucleotides in GNA: probing duplex formation and sensing of copper(II) ions | |
Zhou, Hui1; Ma, Xiaoyan2,3; Wang, Jianpian2; Zhang, Lilu1 | |
刊名 | ORGANIC & BIOMOLECULAR CHEMISTRY
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2009 | |
卷号 | 7期号:11页码:2297-2302 |
ISSN号 | 1477-0520 |
DOI | 10.1039/b900167k |
英文摘要 | The synthesis and evaluation of GNA duplexes containing fluorescent pyrene and pyrene acetylide nucleotides is reported. Interestingly, only the pyrene acetylides, but not the related plain pyrene nucleotides, form strong excimers upon stacking in glycol nucleic acid (GNA) duplexes. The ability of the large pyrene acetylide nucleotide to be accommodated in GNA duplexes opposite an abasic site was investigated by molecular modeling. The interstrand pyrene acetylide excimer formation was used to monitor GNA duplex formation and was applied to the design of a copper(II)-selective "turn-on" fluorescence sensor. |
语种 | 英语 |
出版者 | ROYAL SOC CHEMISTRY |
WOS记录号 | WOS:000266269600010 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/68585] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Zhang, Lilu |
作者单位 | 1.Univ Marburg, Fachbereich Chem, D-35032 Marburg, Germany 2.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zhou, Hui,Ma, Xiaoyan,Wang, Jianpian,et al. Pyrene acetylide nucleotides in GNA: probing duplex formation and sensing of copper(II) ions[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2009,7(11):2297-2302. |
APA | Zhou, Hui,Ma, Xiaoyan,Wang, Jianpian,&Zhang, Lilu.(2009).Pyrene acetylide nucleotides in GNA: probing duplex formation and sensing of copper(II) ions.ORGANIC & BIOMOLECULAR CHEMISTRY,7(11),2297-2302. |
MLA | Zhou, Hui,et al."Pyrene acetylide nucleotides in GNA: probing duplex formation and sensing of copper(II) ions".ORGANIC & BIOMOLECULAR CHEMISTRY 7.11(2009):2297-2302. |
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