Kinetic study of the reaction of chlorine atoms with 3-methyl-3-buten-1-ol

doi:10.1007/s11434-009-0439-1

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	Kinetic study of the reaction of chlorine atoms with 3-methyl-3-buten-1-ol
	Wang Lei; Ge MaoFa; Wang WeiGang
刊名	CHINESE SCIENCE BULLETIN
	2009-10-01
卷号	54 期号:20 页码:3808-3812
关键词	Atmosphereic Chemistry Chloride Atoms Unsaturated Alcohols Gas-phase Reaction Kinetics
ISSN号	1001-6538
DOI	10.1007/s11434-009-0439-1
英文摘要	The reaction of a typical unsaturated alcohol, 3-methyl-3-buten-1-ol (MBO331), with Cl atoms, was investigated for the first time. The reaction was investigated using discharged flow-tube coupled with electron impact mass spectrometer. The experiments were performed over the temperature range of 248 K-298 K and at pressure of 1 torr in He as the bath gas. The obtained kinetic data were used to derive the Arrhenius expression: k(1) = (3.47 +/- 1.21) x 10(-11) exp[(599 +/- 69)/T] cm(3) molecule(-1) s(-1). Finally, atmospheric lifetimes of the MBO331 with respect to OH radicals, NO(3) radicals and Cl atoms have been calculated and the atmospheric implications are considered briefly.
语种	英语
出版者	SCIENCE PRESS
WOS记录号	WOS:000271175500033
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/67975]
专题	中国科学院化学研究所
通讯作者	Ge MaoFa
作者单位	Chinese Acad Sci, Inst Chem, BNLMS, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Wang Lei,Ge MaoFa,Wang WeiGang. Kinetic study of the reaction of chlorine atoms with 3-methyl-3-buten-1-ol[J]. CHINESE SCIENCE BULLETIN,2009,54(20):3808-3812.
APA	Wang Lei,Ge MaoFa,&Wang WeiGang.(2009).Kinetic study of the reaction of chlorine atoms with 3-methyl-3-buten-1-ol.CHINESE SCIENCE BULLETIN,54(20),3808-3812.
MLA	Wang Lei,et al."Kinetic study of the reaction of chlorine atoms with 3-methyl-3-buten-1-ol".CHINESE SCIENCE BULLETIN 54.20(2009):3808-3812.