Cyanide-bridged 1D Mn(III)-Fe(III) bimetallic complexes: synthesis, crystal structure and magnetic properties

doi:10.1039/b9nj00316a

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	Cyanide-bridged 1D Mn(III)-Fe(III) bimetallic complexes: synthesis, crystal structure and magnetic properties
	Kou, Hui-Zhong 1; Ni, Zhong-Hai 1; Liu, Cai-Ming 2; Zhang, De-Qing 2; Cui, Ai-Li 1
刊名	NEW JOURNAL OF CHEMISTRY
	2009
卷号	33 期号:11 页码:2296-2299
ISSN号	1144-0546
DOI	10.1039/b9nj00316a
英文摘要	Cyanide-bridged Mn(III)-Fe(III) complexes have been synthesized in order to find new molecular materials with interesting magnetic properties. 1D complexes of trans-dicyanoferrite(III), [Mn(5-Cl-salen) Fe(bpClb)(CN)(2)]center dot 0.67MeCN center dot 0.5H(2)O (1), [Mn(5-Cl-salen)Fe(bpb)(CN)(2)]center dot 0.5H(2)O center dot MeOH (2), [Mn(5-Br-salen)Fe(bpb)(CN)(2)]center dot 0.5H(2)O center dot MeOH (3), and [Mn(5-Me-salen)Fe(bpb)(CN)(2)]center dot 0.5H(2)O center dot MeOH (4) have been prepared and characterized by X-ray single-crystal structure analysis and magnetic measurements. All complexes possesses 1D chains of alternate [Mn(5-R-salen)](+) and [Fe(bpRb)(CN)(2)](-) units that are linked by two trans-cyanide ligands of [Fe(bpRb)(CN)(2)](-). Magnetic studies reveal that they exhibit overall intermetallic ferromagnetic coupling, while complex 4 shows a frequency-dependent AC magnetic susceptibility typical of a single-chain magnet.
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000271191300013
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/67871]
专题	中国科学院化学研究所
通讯作者	Kou, Hui-Zhong
作者单位	1.Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Ctr Mol Sci, Inst Chem, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Kou, Hui-Zhong,Ni, Zhong-Hai,Liu, Cai-Ming,et al. Cyanide-bridged 1D Mn(III)-Fe(III) bimetallic complexes: synthesis, crystal structure and magnetic properties[J]. NEW JOURNAL OF CHEMISTRY,2009,33(11):2296-2299.
APA	Kou, Hui-Zhong,Ni, Zhong-Hai,Liu, Cai-Ming,Zhang, De-Qing,&Cui, Ai-Li.(2009).Cyanide-bridged 1D Mn(III)-Fe(III) bimetallic complexes: synthesis, crystal structure and magnetic properties.NEW JOURNAL OF CHEMISTRY,33(11),2296-2299.
MLA	Kou, Hui-Zhong,et al."Cyanide-bridged 1D Mn(III)-Fe(III) bimetallic complexes: synthesis, crystal structure and magnetic properties".NEW JOURNAL OF CHEMISTRY 33.11(2009):2296-2299.