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Tailoring Nanowire Network Morphology and Charge Carrier Mobility of Poly(3-hexylthiophene)/C-60 Films
Liu, Weili1,2; Liu, Ruigang1; Wang, Wen1,2; Li, Weiwei1,2; Liu, Wenyong1,2; Zheng, Kai1,2; Ma, Lin1,2; Tian, Ye1,2; Bo, Zhishan1; Huang, Yong1
刊名JOURNAL OF PHYSICAL CHEMISTRY C
2009-07-02
卷号113期号:26页码:11385-11389
ISSN号1932-7447
DOI10.1021/jp900042h
英文摘要We used solvent-vapor treatment methods to determine nanoscale phase separation and thus tailor the charge mobility of the poly(3-hexylthiophene)/fullerene (P3HT/C-60) blend films. The nanowires obtained by chloroform vapor treatment are rich in C-60, whereas the nanowires obtained by 1,2-dichlorobenzene (DCB) vapor treatment are rich in P3HT. The treated blends offer far superior hole transport than the untreated blends, which is attributed to nanoscale phase separation and a three-dimensional network containing C-60 or P3HT nanowires. Meanwhile, the electrically bicontinuous nanoscale morphology realized by controlling the crystallinity of P3HT and C-60 using different solvent-vapor results in enhanced absorption in visible light without further heat treatment or preparation in both cases. Solar cells fabricating from the films after treatment show several-fold improvements in power conversion efficiency compared to that of devices having films without treatment.
语种英语
出版者AMER CHEMICAL SOC
WOS记录号WOS:000267324600032
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/67633]  
专题中国科学院化学研究所
通讯作者Liu, Ruigang
作者单位1.Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Liu, Weili,Liu, Ruigang,Wang, Wen,et al. Tailoring Nanowire Network Morphology and Charge Carrier Mobility of Poly(3-hexylthiophene)/C-60 Films[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2009,113(26):11385-11389.
APA Liu, Weili.,Liu, Ruigang.,Wang, Wen.,Li, Weiwei.,Liu, Wenyong.,...&Huang, Yong.(2009).Tailoring Nanowire Network Morphology and Charge Carrier Mobility of Poly(3-hexylthiophene)/C-60 Films.JOURNAL OF PHYSICAL CHEMISTRY C,113(26),11385-11389.
MLA Liu, Weili,et al."Tailoring Nanowire Network Morphology and Charge Carrier Mobility of Poly(3-hexylthiophene)/C-60 Films".JOURNAL OF PHYSICAL CHEMISTRY C 113.26(2009):11385-11389.
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