Synthesis of a graft polymer PVAc-g-[P(AN-r-BVE)-b-PCHO] in "one-step" by radical/cationic transformation polymerization and coupling reaction

doi:10.1016/j.polymer.2009.06.002

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	Synthesis of a graft polymer PVAc-g-[P(AN-r-BVE)-b-PCHO] in "one-step" by radical/cationic transformation polymerization and coupling reaction
	Lai, Renfu 1; Guo, Haiqing 1; Kamachi, Mikuharu 2
刊名	POLYMER
	2009-07-17
卷号	50 期号:15 页码:3582-3586
关键词	One-step Graft Polymer Transformation Polymerization
ISSN号	0032-3861
DOI	10.1016/j.polymer.2009.06.002
英文摘要	This article reports a new "one-step" synthesis of graft polymers based on the radical/cationic transformation polymerization. Using the synthetic method proposed, a graft polymer (PVAc-g-[P(AN-r-BVE)-b-PCHO]) consisting of a partly hydrolyzed poly(vinyl acetate) (PVAc-OH) backbone and block polymer grafts of acrylonitrile/n-butyl vinyl ether random copolymer (P(AN-r-BVE)) and poly(cyclohexene oxide) (PCHO) was synthesized in situ by radical/cationic transformation polymerization of a mixture of AN/ BVE/CHO in the presence of PVAc-OH. The graft polymer, PVAc-g-[P(AN-r-BVE)-b-PCHO], was fully characterized by (1)H NIMR, IR. gel permeation chromatography and differential scanning calorimetry. The graft polymer, PVAc-g-[P(AN-r-BVE)-b-PCHO], was hydrolyzed with NaOH to form a poly(vinyl alcohol)-based amphiphilic graft polymer, PVA-g-[P(AN-r-BVE)-b-PCHO]. The aggregation behavior of the amphiphilic graft polymer was investigated briefly by atomic force microscopy and dynamic light scattering measurements. (C) 2009 Elsevier Ltd. All rights reserved.
语种	英语
出版者	ELSEVIER SCI LTD
WOS记录号	WOS:000268306700022
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/67145]
专题	中国科学院化学研究所
通讯作者	Guo, Haiqing
作者单位	1.Peking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China 2.Fukui Univ Technol, Dept Appl Phys & Chem, Fukui 9100028, Japan
推荐引用方式 GB/T 7714	Lai, Renfu,Guo, Haiqing,Kamachi, Mikuharu. Synthesis of a graft polymer PVAc-g-[P(AN-r-BVE)-b-PCHO] in "one-step" by radical/cationic transformation polymerization and coupling reaction[J]. POLYMER,2009,50(15):3582-3586.
APA	Lai, Renfu,Guo, Haiqing,&Kamachi, Mikuharu.(2009).Synthesis of a graft polymer PVAc-g-[P(AN-r-BVE)-b-PCHO] in "one-step" by radical/cationic transformation polymerization and coupling reaction.POLYMER,50(15),3582-3586.
MLA	Lai, Renfu,et al."Synthesis of a graft polymer PVAc-g-[P(AN-r-BVE)-b-PCHO] in "one-step" by radical/cationic transformation polymerization and coupling reaction".POLYMER 50.15(2009):3582-3586.