VIBRATIONAL EXCITATION OF OH(v <= 3) FROM THE REACTION OF O(D-1) + Si(CH3)(3)Cl

doi:10.3866/PKU.WHXB19930404

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	VIBRATIONAL EXCITATION OF OH(v <= 3) FROM THE REACTION OF O(D-1) + Si(CH3)(3)Cl
	Li Hongzhi; Wang Xuebin; Kong Fanao; Zhu Qihe
刊名	ACTA PHYSICO-CHIMICA SINICA
	1993
卷号	9 期号:4 页码:447-449
关键词	Intramolecular Energy Transfer Ir Emission Spectroscopy Heavy Atom Effect Chlorotrimethylsilane
ISSN号	1000-6818
DOI	10.3866/PKU.WHXB19930404
英文摘要	The vibrationally excited OH(v) from the reaction of O(D-1)+Si(CH3)(3)Cl was observed by UV lasre photolysis/FTIR emission spectroscopy. The vibrational number was only up to 3 with a ratio of 1:0.3:0 1 for v=1:2:3. Comparing this result with the similar reaction of O(D-1) + Si(CH3)(4) which OH(v) vibrational number was high up to 4 with a ration of 1:1:1:0:3 for v=1:2:3:4 under the same experimental conditions, it was found that the substitution of Cl for CH3 affected the extent of heavy Si atom blooking the energy migratio in a molecule. This results identifies the prediction that the characteristic of electrons in central atom plays an important role in intramolecular energy transfer.
语种	英语
出版者	PEKING UNIV PRESS
WOS记录号	WOS:000207577600004
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/66683]
专题	中国科学院化学研究所
通讯作者	Li Hongzhi
作者单位	Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Li Hongzhi,Wang Xuebin,Kong Fanao,et al. VIBRATIONAL EXCITATION OF OH(v <= 3) FROM THE REACTION OF O(D-1) + Si(CH3)(3)Cl[J]. ACTA PHYSICO-CHIMICA SINICA,1993,9(4):447-449.
APA	Li Hongzhi,Wang Xuebin,Kong Fanao,&Zhu Qihe.(1993).VIBRATIONAL EXCITATION OF OH(v <= 3) FROM THE REACTION OF O(D-1) + Si(CH3)(3)Cl.ACTA PHYSICO-CHIMICA SINICA,9(4),447-449.
MLA	Li Hongzhi,et al."VIBRATIONAL EXCITATION OF OH(v <= 3) FROM THE REACTION OF O(D-1) + Si(CH3)(3)Cl".ACTA PHYSICO-CHIMICA SINICA 9.4(1993):447-449.