Synthesis, structures, and properties of peripheral o-dimethoxy-substituted pentiptycene quinones and their o-quinone derivatives

doi:10.1016/j.tet.2009.07.090

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	Synthesis, structures, and properties of peripheral o-dimethoxy-substituted pentiptycene quinones and their o-quinone derivatives
	Cao, Jing 1,2; Lu, Hai-Yan 2; Chen, Chuan-Feng 1
刊名	TETRAHEDRON
	2009-09-26
卷号	65 期号:39 页码:8104-8112
关键词	Pentiptycene Quinones Synthesis And Structure Self-assembly In The Solid State Photo-physical Property Electrochemistry Property
ISSN号	0040-4020
DOI	10.1016/j.tet.2009.07.090
英文摘要	A series of peripheral o-dimethoxy-substituted pentiptycene quinones and their o-quinone derivatives have been synthesized. Especially, it was found that if two o-dimethoxybenzene moieties were situated at the same side of the pentiptycene quinones, one of them was only oxidized by excess CAN in aqueous acetonitrile. Moreover, the pentiptycene quinones with unique 3D rigid structure could all self-assemble into a 3D microporous structure in the solid state. For the pentiptycene quinones containing the dimethoxybenzene unit(s) and the quinone group(s) simultaneously, interesting intramolecular charge transfer interactions and electrochemical properties were also shown. These peripheral-substituted pentiptycene quinones and their o-quinone derivatives can be used as new useful building blocks and will find wide applications in material science and host-guest chemistry. (C) 2009 Elsevier Ltd. All rights reserved.
语种	英语
出版者	PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号	WOS:000270121400004
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/66435]
专题	中国科学院化学研究所
通讯作者	Chen, Chuan-Feng
作者单位	1.Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Cao, Jing,Lu, Hai-Yan,Chen, Chuan-Feng. Synthesis, structures, and properties of peripheral o-dimethoxy-substituted pentiptycene quinones and their o-quinone derivatives[J]. TETRAHEDRON,2009,65(39):8104-8112.
APA	Cao, Jing,Lu, Hai-Yan,&Chen, Chuan-Feng.(2009).Synthesis, structures, and properties of peripheral o-dimethoxy-substituted pentiptycene quinones and their o-quinone derivatives.TETRAHEDRON,65(39),8104-8112.
MLA	Cao, Jing,et al."Synthesis, structures, and properties of peripheral o-dimethoxy-substituted pentiptycene quinones and their o-quinone derivatives".TETRAHEDRON 65.39(2009):8104-8112.