Lanthanide-alkali metals-oxalates coordination polymers: Synthesis and structures of [Nd(C2O4)(1.5)(H2O)(3)] center dot 2H(2)O, Nd(C2O4)(CH3COO)(H2O), KLn(C2O4)(2)(H2O)(4) (Ln = Y, Tb)

doi:10.1016/j.ica.2008.05.029

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	Lanthanide-alkali metals-oxalates coordination polymers: Synthesis and structures of [Nd(C2O4)(1.5)(H2O)(3)] center dot 2H(2)O, Nd(C2O4)(CH3COO)(H2O), KLn(C2O4)(2)(H2O)(4) (Ln = Y, Tb)
	Zhang, Xingjing 1; Xing, Yongheng 1; Wang, Chunguang 1; Han, Jing 1; Li, Jing 1; Ge, Maofa 2; Zeng, Xiaoqing 2; Niu, Shuyun 1
刊名	INORGANICA CHIMICA ACTA
	2009-03-02
卷号	362 期号:4 页码:1058-1064
关键词	Lanthanide Oxalate Synthesis Structure Spectrum
ISSN号	0020-1693
DOI	10.1016/j.ica.2008.05.029
英文摘要	Two new lanthanide-oxalates coordination polymers, [Nd(C2O4)(1.5)(H2O)(3)] center dot 2H(2)O 1, Nd(C2O4)(CH3-COO)(H2O) 2, and two new lanthanide-alkali-oxalates coordination polymers KY(C2O4)(2)(H2O)(4) 3, KTb(C2O4)(2)(H2O)(4) 4, have been synthesized under hydrothermal conditions and their structures were determined by single-crystal X-ray diffraction. Structural analysis shows that the two-dimensional (2D) layer structure of complex 1 is built up by the linkages of lanthanide atoms and the oxygen atoms of the bischelating oxalate ligands. In complex 2, for introducing of acetate groups, a 3D network with parallelogram channels (6.3 x 9.4 angstrom) of complex 2 was obtained. The 3D structures of complexes 3 and 4 contain a channel. filled with lattice water molecules, and the potassium atoms are located in the framework. (C) 2008 Elsevier B. V. All rights reserved.
语种	英语
出版者	ELSEVIER SCIENCE SA
WOS记录号	WOS:000263322200005
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/66421]
专题	中国科学院化学研究所
通讯作者	Xing, Yongheng
作者单位	1.Liaoning Normal Univ, Coll Chem & Chem Engn, Dalian 116029, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Xingjing,Xing, Yongheng,Wang, Chunguang,et al. Lanthanide-alkali metals-oxalates coordination polymers: Synthesis and structures of [Nd(C2O4)(1.5)(H2O)(3)] center dot 2H(2)O, Nd(C2O4)(CH3COO)(H2O), KLn(C2O4)(2)(H2O)(4) (Ln = Y, Tb)[J]. INORGANICA CHIMICA ACTA,2009,362(4):1058-1064.
APA	Zhang, Xingjing.,Xing, Yongheng.,Wang, Chunguang.,Han, Jing.,Li, Jing.,...&Niu, Shuyun.(2009).Lanthanide-alkali metals-oxalates coordination polymers: Synthesis and structures of [Nd(C2O4)(1.5)(H2O)(3)] center dot 2H(2)O, Nd(C2O4)(CH3COO)(H2O), KLn(C2O4)(2)(H2O)(4) (Ln = Y, Tb).INORGANICA CHIMICA ACTA,362(4),1058-1064.
MLA	Zhang, Xingjing,et al."Lanthanide-alkali metals-oxalates coordination polymers: Synthesis and structures of [Nd(C2O4)(1.5)(H2O)(3)] center dot 2H(2)O, Nd(C2O4)(CH3COO)(H2O), KLn(C2O4)(2)(H2O)(4) (Ln = Y, Tb)".INORGANICA CHIMICA ACTA 362.4(2009):1058-1064.