Fluorescent Alteration on a Bistable Molecular Shuttle

doi:10.1002/cphc.200900228

CORC > 化学研究所 > 中国科学院化学研究所

	Fluorescent Alteration on a Bistable Molecular Shuttle
	Zhou, Weidong 1,2; Zhang, Shuai 3; Li, Guoxing 1,2; Zhao, Yingjie 1,2; Shi, Zhiqiang 3; Liu, Huibiao 1,2; Li, Yuliang 1,2
刊名	CHEMPHYSCHEM
	2009-08-24
卷号	10 期号:12 页码:2066-2072
关键词	Electron Transfer Fluorescence Macrocycles Molecular Motors Rotaxane
ISSN号	1439-4235
DOI	10.1002/cphc.200900228
英文摘要	Solvent driven molecular shuttles containing a pyrene-connected macrocycle and an intramolecular charge-transfer (ICT) chromophore stopper are constructed. In one of the molecular shuttles, a long C-10 chain is introduced in the thread to separate the peptide station and the ICT stopper. The macrocycle stays in the peptide station in apolar solvents and moves to the C10-chain station in highly polar solvents. This moving process alters the electronic interaction between the pyrene unit in the macrocycle and the ICT stopper, which induces the change of the pyrene fluorescence emission. The molecular shuttle exhibits stronger emission when the macrocycle is adjacent to the ICT stopper.
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000269398800017
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/66043]
专题	中国科学院化学研究所
通讯作者	Li, Yuliang
作者单位	1.Chinese Acad Sci, Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100190, Peoples R China 3.Shandong Normal Univ, Dept Chem, Jianan 250014, Peoples R China
推荐引用方式 GB/T 7714	Zhou, Weidong,Zhang, Shuai,Li, Guoxing,et al. Fluorescent Alteration on a Bistable Molecular Shuttle[J]. CHEMPHYSCHEM,2009,10(12):2066-2072.
APA	Zhou, Weidong.,Zhang, Shuai.,Li, Guoxing.,Zhao, Yingjie.,Shi, Zhiqiang.,...&Li, Yuliang.(2009).Fluorescent Alteration on a Bistable Molecular Shuttle.CHEMPHYSCHEM,10(12),2066-2072.
MLA	Zhou, Weidong,et al."Fluorescent Alteration on a Bistable Molecular Shuttle".CHEMPHYSCHEM 10.12(2009):2066-2072.