Synthesis and Characterizations of Graft Copolymer of Ethylcellulose with Poly(caprolactone monoacrylate)

doi:10.1295/polymj.PJ2008032

CORC > 化学研究所 > 中国科学院化学研究所

	Synthesis and Characterizations of Graft Copolymer of Ethylcellulose with Poly(caprolactone monoacrylate)
	Wang, Dongshan 1,2; Chen, Changzhong 1,3; Xuan, Yingnan 1; Huang, Yong 1,4; Shen, Jiarui 2
刊名	POLYMER JOURNAL
	2009
卷号	41 期号:1 页码:69-73
关键词	Ethylcellulose Graft Polymer Synthesis Characterization Degradable
ISSN号	0032-3896
DOI	10.1295/polymj.PJ2008032
英文摘要	Ethylcellulose grafting polycaprolactone monoacrylate copolymer (EC-g-PCLA) was synthesized by a two-step reaction of ethylcellulose (EC) with poly(caprolactone monoacrylate) (PCLA). The isocyanate-terminated intermediate (NCOPCLA) was prepared firstly and then it was grafted onto ethylcellulose chains. The structure analysis of the copolymers from the FTIR, (1)H NMR and (13)C NMR indicated that PCLA was connected to EC by chemical bonding. The flow temperature of graft copolymer was lower than that of the pure EC and decreased with increasing the grafting percentage. Outdoor soil burial and active sludge tests indicated that the graft copolymer has biodegradability in natural conditions.
语种	英语
出版者	SOC POLYMER SCIENCE JAPAN
WOS记录号	WOS:000264050400012
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/65881]
专题	中国科学院化学研究所
通讯作者	Huang, Yong
作者单位	1.Chinese Acad Sci, Guangzhou Inst Chem, Key Lab Cellulose & Lignocellulos Chem, Guangzhou 510650, Peoples R China 2.S China Univ Technol, Coll Mat Sci & Engn, Guangzhou 510641, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 4.Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Wang, Dongshan,Chen, Changzhong,Xuan, Yingnan,et al. Synthesis and Characterizations of Graft Copolymer of Ethylcellulose with Poly(caprolactone monoacrylate)[J]. POLYMER JOURNAL,2009,41(1):69-73.
APA	Wang, Dongshan,Chen, Changzhong,Xuan, Yingnan,Huang, Yong,&Shen, Jiarui.(2009).Synthesis and Characterizations of Graft Copolymer of Ethylcellulose with Poly(caprolactone monoacrylate).POLYMER JOURNAL,41(1),69-73.
MLA	Wang, Dongshan,et al."Synthesis and Characterizations of Graft Copolymer of Ethylcellulose with Poly(caprolactone monoacrylate)".POLYMER JOURNAL 41.1(2009):69-73.