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Solidification of liquid electrolyte with imidazole polymers for quasi-solid-state dye-sensitized solar cells
Wang, Miao1,2; Lin, Yuan1; Zhou, Xiaowen1; Xiao, Xurui1; Yang, Lei1; Feng, Shujing1; Li, Xueping1
刊名MATERIALS CHEMISTRY AND PHYSICS
2008-01-15
卷号107期号:1页码:61-66
关键词Solidification Polymers Dye-sensitized Solar Cells Electrochemical Properties
ISSN号0254-0584
DOI10.1016/j.matchemphys.2007.06.041
英文摘要Quasi-solid-state electrolytes were prepared by employing the imidazole polymers to solidify the liquid electrolyte containing lithium iodide, iodine and ethylene carbonate (EC)/propylene carbonate (PC) mixed solvent. The ionic conductivity and diffusion behavior of triiodide in the quasi-solid-state electrolytes were examined in terms of the polymer content. Application of the quasi-solid-state electrolytes to the dye-sensitized solar cells, the maximum energy conversion efficiency of 7.6% (AM 1.5, 100 mW cm(-2)) was achieved. The dependence of the photovoltaic performance on the polymer content and on the different anions of the imidazole polymers was studied by electrochemical impedance spectroscopy and cyclic voltammetry. The results indicate the charge transfer behaviors occurred at nanocrystalline TiO2/electrolyte and Pt/electrolyte interface play an important role in influencing the photovoltaic performance of quasi-solid-state dye-sensitized solar cells. (c) 2007 Elsevier B.V. All rights reserved.
语种英语
出版者ELSEVIER SCIENCE SA
WOS记录号WOS:000252333300013
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/65271]  
专题中国科学院化学研究所
通讯作者Lin, Yuan
作者单位1.Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Wang, Miao,Lin, Yuan,Zhou, Xiaowen,et al. Solidification of liquid electrolyte with imidazole polymers for quasi-solid-state dye-sensitized solar cells[J]. MATERIALS CHEMISTRY AND PHYSICS,2008,107(1):61-66.
APA Wang, Miao.,Lin, Yuan.,Zhou, Xiaowen.,Xiao, Xurui.,Yang, Lei.,...&Li, Xueping.(2008).Solidification of liquid electrolyte with imidazole polymers for quasi-solid-state dye-sensitized solar cells.MATERIALS CHEMISTRY AND PHYSICS,107(1),61-66.
MLA Wang, Miao,et al."Solidification of liquid electrolyte with imidazole polymers for quasi-solid-state dye-sensitized solar cells".MATERIALS CHEMISTRY AND PHYSICS 107.1(2008):61-66.
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