Detection of trace Hg(2+) via induced circular dichroism of DNA wrapped around single-walled carbon nanotubes | |
Gao, Xueyun1; Xing, Gengmei1; Yang, Yanlian2; Shi, Xiaoli3; Liu, Ru1; Chu, Weiguo2; Jing, Long1; Zhao, Feng1; Ye, Chang1; Yuan, Hui1 | |
刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY |
2008-07-23 | |
卷号 | 130期号:29页码:9190-+ |
ISSN号 | 0002-7863 |
DOI | 10.1021/ja801793k |
英文摘要 | The strongly induced circular dichroism (ICD) signals of DNA wrapped around single-walled carbon nanotubes I are shown by the Synchrotron Radiation Facility. In solution, trace amounts of Hg ions have a strong affinity to bind the nucleic bases of DNA-SWCNTs via a pseudo-first-order kinetic reaction. The Hg binding to the bases of DNA results in partial DNA disassociation from the SWCNTs. Such disassociation of DNA from the SWCNTs will decrease the coupling effects of the transition dipole moments between DNA and SWCNTs, thus inducing the ICD signal of DNA-SWCNTs to decrease significantly. Herein, the ICD of DNA-SWCNTs is applied to detect the concentration of Hg ions at. |
语种 | 英语 |
出版者 | AMER CHEMICAL SOC |
WOS记录号 | WOS:000257796500006 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/64869] |
专题 | 中国科学院化学研究所 |
通讯作者 | Gao, Xueyun |
作者单位 | 1.Inst High Energy Phys, Lab Bioenvironm Effects Nanomat & Nanosafety, Beijing 100049, Peoples R China 2.Natl Ctr Nanosci & Technol, Beijing 100080, Peoples R China 3.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Mol Nanostruct & Nanotechnol, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Gao, Xueyun,Xing, Gengmei,Yang, Yanlian,et al. Detection of trace Hg(2+) via induced circular dichroism of DNA wrapped around single-walled carbon nanotubes[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2008,130(29):9190-+. |
APA | Gao, Xueyun.,Xing, Gengmei.,Yang, Yanlian.,Shi, Xiaoli.,Liu, Ru.,...&Zhao, Yuliang.(2008).Detection of trace Hg(2+) via induced circular dichroism of DNA wrapped around single-walled carbon nanotubes.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,130(29),9190-+. |
MLA | Gao, Xueyun,et al."Detection of trace Hg(2+) via induced circular dichroism of DNA wrapped around single-walled carbon nanotubes".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 130.29(2008):9190-+. |
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