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Detection of trace Hg(2+) via induced circular dichroism of DNA wrapped around single-walled carbon nanotubes
Gao, Xueyun1; Xing, Gengmei1; Yang, Yanlian2; Shi, Xiaoli3; Liu, Ru1; Chu, Weiguo2; Jing, Long1; Zhao, Feng1; Ye, Chang1; Yuan, Hui1
刊名JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
2008-07-23
卷号130期号:29页码:9190-+
ISSN号0002-7863
DOI10.1021/ja801793k
英文摘要The strongly induced circular dichroism (ICD) signals of DNA wrapped around single-walled carbon nanotubes I are shown by the Synchrotron Radiation Facility. In solution, trace amounts of Hg ions have a strong affinity to bind the nucleic bases of DNA-SWCNTs via a pseudo-first-order kinetic reaction. The Hg binding to the bases of DNA results in partial DNA disassociation from the SWCNTs. Such disassociation of DNA from the SWCNTs will decrease the coupling effects of the transition dipole moments between DNA and SWCNTs, thus inducing the ICD signal of DNA-SWCNTs to decrease significantly. Herein, the ICD of DNA-SWCNTs is applied to detect the concentration of Hg ions at.
语种英语
出版者AMER CHEMICAL SOC
WOS记录号WOS:000257796500006
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/64869]  
专题中国科学院化学研究所
通讯作者Gao, Xueyun
作者单位1.Inst High Energy Phys, Lab Bioenvironm Effects Nanomat & Nanosafety, Beijing 100049, Peoples R China
2.Natl Ctr Nanosci & Technol, Beijing 100080, Peoples R China
3.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Mol Nanostruct & Nanotechnol, Beijing 100080, Peoples R China
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GB/T 7714
Gao, Xueyun,Xing, Gengmei,Yang, Yanlian,et al. Detection of trace Hg(2+) via induced circular dichroism of DNA wrapped around single-walled carbon nanotubes[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2008,130(29):9190-+.
APA Gao, Xueyun.,Xing, Gengmei.,Yang, Yanlian.,Shi, Xiaoli.,Liu, Ru.,...&Zhao, Yuliang.(2008).Detection of trace Hg(2+) via induced circular dichroism of DNA wrapped around single-walled carbon nanotubes.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,130(29),9190-+.
MLA Gao, Xueyun,et al."Detection of trace Hg(2+) via induced circular dichroism of DNA wrapped around single-walled carbon nanotubes".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 130.29(2008):9190-+.
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