Photoluminescence and electroluminescence from a hybrid of lumogen red in nanoporous-silica

doi:10.1166/jnn.2008.323

CORC > 化学研究所 > 中国科学院化学研究所

	Photoluminescence and electroluminescence from a hybrid of lumogen red in nanoporous-silica
	Wang, Junling 1; He, Zhiqun 1; Wang, Yongsheng 1; Mu, Linping 1; Cao, Anmin 2
刊名	JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
	2008-03-01
卷号	8 期号:3 页码:1336-1340
关键词	Lumogen Red Nanoporous Silica Photoluminescence Electroluminescence White
ISSN号	1533-4880
DOI	10.1166/jnn.2008.323
英文摘要	In this paper white electroluminescence from a lumogen red-doped nanoporous silica matrix is presented. The matrix was prepared using a sol-gel process, and lumogen red-a perylene derivative-was doped at a number of concentrations. The photoluminescence and electroluminescence of the lumogen red-doped nanoporous-silica composite were investigated in detail. The structures, surface morphology, and optical properties of the nanoporous silica composites were investigated. The average pore size of the nanoporous-silica matrix was similar to 5 nm. The absorption spectra of the lumogen red in the nanoporous-silica matrix were broader than those from solution specimens. The photoluminescence of the lumogen red-doped nanoporous-silica matrix depended strongly on the excitation wavelengths. When excited at relatively longer wavelengths, e.g., 467 nm, the emissions peaked at constant positions (similar to 608 nm) for all cases, except a small shift to the red from its solution 601 nm. However, if excited at a shorter wavelength in the range of 200-400 nm, additional blue emissions were observed, which were particularly strong and suggested defect centers of the nanoporous-silica matrix. The electroluminescence from a single-layered sandwich device consisting of the lumogen red-doped nanoporous-silica was interesting. When driving with an AC electric field, electroluminescence spectra covered a whole spectral range, consisting of the red emission from lumogen red and the blue and green emission from the nanoporous silica matrix. In this way, we actually achieved a white electroluminescence from this hybrid organic and silica device with a color coordinate, CIE [x, y] = [0.30, 0.35] at a driving electric field of 3.0 x 10(6) V/cm. This was a first attempt to investigate electroluminescence from an organic dye-doped nanoporous silica matrix.
语种	英语
出版者	AMER SCIENTIFIC PUBLISHERS
WOS记录号	WOS:000254540700045
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/64475]
专题	中国科学院化学研究所
通讯作者	He, Zhiqun
作者单位	1.Beijing Jiaotong Univ, Key Lab Luminescence & Opt Informat, Minist Educ, Inst Optoelect Technol, Beijing 100044, Peoples R China 2.Chinese Acad Sci, Key Lab Mol Nanostruct & Nanotechnol, Inst Chem, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Wang, Junling,He, Zhiqun,Wang, Yongsheng,et al. Photoluminescence and electroluminescence from a hybrid of lumogen red in nanoporous-silica[J]. JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY,2008,8(3):1336-1340.
APA	Wang, Junling,He, Zhiqun,Wang, Yongsheng,Mu, Linping,&Cao, Anmin.(2008).Photoluminescence and electroluminescence from a hybrid of lumogen red in nanoporous-silica.JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY,8(3),1336-1340.
MLA	Wang, Junling,et al."Photoluminescence and electroluminescence from a hybrid of lumogen red in nanoporous-silica".JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY 8.3(2008):1336-1340.