Synthesis and properties of novel polyimides from 3-(4-aminophenylthio)-n-aminophthalimide | |
Yan, Jingling1,2; Wang, Zhen1; Lv, Changli1; Yang, Huili1; Shang, Zhenping1,2; Gao, Lianxun1; Ding, Mengxian1 | |
刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
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2008-10-15 | |
卷号 | 110期号:2页码:706-711 |
关键词 | Polyimides Structure-property Relations Synthesis |
ISSN号 | 0021-8995 |
英文摘要 | A novel, asymmetric diamine 3-(4-amino-phenylithio)-N-aminophthalmide, was prepared from 3-chloro-N-aminophthalmide and 4-aminobenzenethiol. The structure of the diamine was determined via IR and H-1-NMR spectroscopy and elemental analysis. A series of polyimides were synthesized from 3-(4-aminophynylthio)-N-aminophthalmide and aromatic dianhydries by a conventional two-step method in N,N-dimethylacetamide and by a one-step method in phenols. These polymidies showed good solubility in 1-methyl-2-pyrrolidinone, m-cremsol, and p-chlorophenol, except polymide from pyromellitic dianhydride, which was only soluble in p-chlorophenol. The 5% weight loss temperatures of these polyimides ranged from 460 to 498 C in air. Dynamic mechanical thermal analysis indicated that the glass-transition temperatures of the polyimides were in the range 278-395 degrees C. The tensile strengths at break, moduli, and elongations of these polyimides were 146-178 MPa, 1.95-2.58 GPa, and 9.1-13.3%, respectively. Compared with corresponding polyimides from 4,4'-diamidophenyl ether, these polymers showed enhanced solubility and higher glass-transition temperatures. (C) 2008 Wiley Periodicals, Inc. J Appl Polym Sci 110:706-711, 2008 |
语种 | 英语 |
出版者 | JOHN WILEY & SONS INC |
WOS记录号 | WOS:000258633900009 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/64125] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Ding, Mengxian |
作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Yan, Jingling,Wang, Zhen,Lv, Changli,et al. Synthesis and properties of novel polyimides from 3-(4-aminophenylthio)-n-aminophthalimide[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2008,110(2):706-711. |
APA | Yan, Jingling.,Wang, Zhen.,Lv, Changli.,Yang, Huili.,Shang, Zhenping.,...&Ding, Mengxian.(2008).Synthesis and properties of novel polyimides from 3-(4-aminophenylthio)-n-aminophthalimide.JOURNAL OF APPLIED POLYMER SCIENCE,110(2),706-711. |
MLA | Yan, Jingling,et al."Synthesis and properties of novel polyimides from 3-(4-aminophenylthio)-n-aminophthalimide".JOURNAL OF APPLIED POLYMER SCIENCE 110.2(2008):706-711. |
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