Synthesis and magnetism of an inorganic-organic nanocomposite: Nitronyl-nitroxide radical intercalated into layered MnPS3

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	Synthesis and magnetism of an inorganic-organic nanocomposite: Nitronyl-nitroxide radical intercalated into layered MnPS3
	Zhou Hui-Qiong 1; Su Xu 1; Chen Xing-Guo 1; Inokuchi, Makoto 2; Zhang De-Qing 3; Qin Jin-Gui 1
刊名	CHINESE JOURNAL OF INORGANIC CHEMISTRY
	2008-08-10
卷号	24 期号:8 页码:1261-1264
关键词	Intercalation Nitrorryl Nitroxide Radical Layered Mnps3 Magnetic Property
ISSN号	1001-4861
英文摘要	The synthesis and magnetism of an intercalation compound were studied based on 2-(4'-N-methylypridinium)-4,4,5,5-tetramethyl-imidazolinyl-1-oxyl-3-oxide (Methylpyridinium nitronyl nitroxide, MPYNN) radical into layered MnPS3. The lattice expansion of 0.56 nm suggests that the guest molecule plane of pyridine in MPYNN is arranged almost perpendicular to the host layer. Magnetic measurements by SQUID indicates that the intercalation compound of (MPYNN)(0.14)Mn0.93PS3 exhibits paramagnetism above 10 K, and then spontaneous magnetization occurs at 7 K.
语种	英语
出版者	CHINESE CHEMICAL SOC
WOS记录号	WOS:000258639900012
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/64111]
专题	中国科学院化学研究所
通讯作者	Chen Xing-Guo
作者单位	1.Wuhan Univ, Hubei Key Lab Organ & Polymer Optoelect Mat, Dept Chem, Wuhan 43007, Peoples R China 2.Tokyo Univ Sci, Dept Mat Sci & Environm Engn, Yamaguchi 7560884, Japan 3.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Zhou Hui-Qiong,Su Xu,Chen Xing-Guo,et al. Synthesis and magnetism of an inorganic-organic nanocomposite: Nitronyl-nitroxide radical intercalated into layered MnPS3[J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY,2008,24(8):1261-1264.
APA	Zhou Hui-Qiong,Su Xu,Chen Xing-Guo,Inokuchi, Makoto,Zhang De-Qing,&Qin Jin-Gui.(2008).Synthesis and magnetism of an inorganic-organic nanocomposite: Nitronyl-nitroxide radical intercalated into layered MnPS3.CHINESE JOURNAL OF INORGANIC CHEMISTRY,24(8),1261-1264.
MLA	Zhou Hui-Qiong,et al."Synthesis and magnetism of an inorganic-organic nanocomposite: Nitronyl-nitroxide radical intercalated into layered MnPS3".CHINESE JOURNAL OF INORGANIC CHEMISTRY 24.8(2008):1261-1264.