Synthesis and thermal properties of polythioetherimides derived from 4,4'-[p-thiobis(phenylenesulfanyl)]diphthalic anhydride and various aromatic diamines | |
Liu, Jin-Gang2; Shibasaki, Yuji2; Ando, Shinji2; Ueda, Mitsuru2 | |
刊名 | HIGH PERFORMANCE POLYMERS |
2008-04-01 | |
卷号 | 20期号:2页码:221-237 |
关键词 | Polythioetherimide Thermal Stability Thioether High Refractive Index |
ISSN号 | 0954-0083 |
DOI | 10.1177/0954008307082508 |
英文摘要 | An asymmetrical aromatic diamine, 1-(4'-aminophenoxy)-4-(4'-aminophenylenesulfanyl) benzene (OSDA) was synthesized. A series of polythioetherimides (PTEIs) were prepared from a thioether-bridged aromatic dianhydride 4,4'-[p-thiobis(phenylenesulfanyl)]diphthalic anhydride (3SDEA) and various aromatic diamines having ether or thioether linkages between phenylene rings by a two-step poly-condensation procedure via their soluble poly(amic acid) (PAA) precursors. Medium to high molecular weight PAAs were obtained with inherent viscosities near or higher than 1.0 dL g(-1), which is high enough to afford flexible and tough PTEI films except for PI-2 (3SDEA-134APB) and PI-6 (3SDEA-m2SPDA) derived from meta-ether-substituted diamines. PI-2 and PI-6 showed some extent of crystallinity compared to the amorphous natures of the other polymers. The PTEI films exhibit good resistance to organic solvents except for PI-3 (3SDEA-133APB), which is soluble in N-methyl-2-pyrrolidinone (NMP) and sulfuric acid at room temperature. The PTEI films show good thermal stability with the 5% weight loss temperatures being above 480 degrees C both in nitrogen and in air. The glass transition temperatures of the PTEIs are in the range of 155 - 191 degrees C, which are lower than those of the commercial polyetherimides due to their plural thioether linkages in the main chains. |
语种 | 英语 |
出版者 | SAGE PUBLICATIONS LTD |
WOS记录号 | WOS:000254575900007 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/64033] |
专题 | 中国科学院化学研究所 |
通讯作者 | Liu, Jin-Gang |
作者单位 | 1.Chinese Acad Sci, Inst Chem, Lab Adv Polymer Mat, Beijing 100080, Peoples R China 2.Tokyo Inst Technol, Dept Organ & Polymer Mat, Meguro Ku, Tokyo 1528552, Japan |
推荐引用方式 GB/T 7714 | Liu, Jin-Gang,Shibasaki, Yuji,Ando, Shinji,et al. Synthesis and thermal properties of polythioetherimides derived from 4,4'-[p-thiobis(phenylenesulfanyl)]diphthalic anhydride and various aromatic diamines[J]. HIGH PERFORMANCE POLYMERS,2008,20(2):221-237. |
APA | Liu, Jin-Gang,Shibasaki, Yuji,Ando, Shinji,&Ueda, Mitsuru.(2008).Synthesis and thermal properties of polythioetherimides derived from 4,4'-[p-thiobis(phenylenesulfanyl)]diphthalic anhydride and various aromatic diamines.HIGH PERFORMANCE POLYMERS,20(2),221-237. |
MLA | Liu, Jin-Gang,et al."Synthesis and thermal properties of polythioetherimides derived from 4,4'-[p-thiobis(phenylenesulfanyl)]diphthalic anhydride and various aromatic diamines".HIGH PERFORMANCE POLYMERS 20.2(2008):221-237. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论