A novel efficient route for preparation of chiral beta-hydroxycarboxylic acid: Asymmetric hydration of unsaturated carboxylic acids catalyzed by heterobimetallic complex wool-palladium-cobalt

doi:10.1016/j.molcata.2006.08.073

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	A novel efficient route for preparation of chiral beta-hydroxycarboxylic acid: Asymmetric hydration of unsaturated carboxylic acids catalyzed by heterobimetallic complex wool-palladium-cobalt
	Wang, Si-Qian ; Wang, Zi-Wei ; Yang, Lin-Chun ; Dong, Jin-Long ; Chi, Cai-Qin ; Sui, Dan-Ni ; Wang, Yong-Zhao ; Ren, Jian-Guo ; Hung, Mei-Yu ; Jiang, Ying-Yan
刊名	JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
	2007-03-01
卷号	264 期号:1-2 页码:60-65
关键词	Chiral Beta-hydroxycarboxylic Acid Asymmetric Hydration Unsaturated Carboxylic Acids Heterobimetallic Complex Wool-palladium-cobalt
ISSN号	1381-1169
DOI	10.1016/j.molcata.2006.08.073
英文摘要	A new bio-polymer heterobimetallic complex wool-Pd-Co is found to be a novel efficient catalyst for asymmetric hydration of unsaturated carboxylic acids with high enantioselectivity by simple and clean process under mild conditions. Chemical and optical yields are affected by some parameters, such as the (Pd + Co) content in wool-Pd-Co, the Co/Pd molar ratio, reaction time, reaction temperature and amount of water. After five-time use of the complex, the chemical and optical yields of the products show no significant changes. Obviously, the methods provide an alternative way to produce chiral beta-hydroxycarboxylic acids. (c) 2006 Elsevier B.V. All rights reserved.
语种	英语
出版者	ELSEVIER SCIENCE BV
WOS记录号	WOS:000244838200011
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/62829]
专题	中国科学院化学研究所
通讯作者	Ren, Jian-Guo
作者单位	1.ShanXi Univ, Coll Chem & Chem Engn, Taiyuan 030006, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Wang, Si-Qian,Wang, Zi-Wei,Yang, Lin-Chun,et al. A novel efficient route for preparation of chiral beta-hydroxycarboxylic acid: Asymmetric hydration of unsaturated carboxylic acids catalyzed by heterobimetallic complex wool-palladium-cobalt[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2007,264(1-2):60-65.
APA	Wang, Si-Qian.,Wang, Zi-Wei.,Yang, Lin-Chun.,Dong, Jin-Long.,Chi, Cai-Qin.,...&Jiang, Ying-Yan.(2007).A novel efficient route for preparation of chiral beta-hydroxycarboxylic acid: Asymmetric hydration of unsaturated carboxylic acids catalyzed by heterobimetallic complex wool-palladium-cobalt.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,264(1-2),60-65.
MLA	Wang, Si-Qian,et al."A novel efficient route for preparation of chiral beta-hydroxycarboxylic acid: Asymmetric hydration of unsaturated carboxylic acids catalyzed by heterobimetallic complex wool-palladium-cobalt".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 264.1-2(2007):60-65.