Spin-canting in a 1D chain Mn(II) complex with alternating double end-on and double end-to-end azido bridging ligands

doi:10.1016/j.inoche.2007.04.004

CORC > 化学研究所 > 中国科学院化学研究所

	Spin-canting in a 1D chain Mn(II) complex with alternating double end-on and double end-to-end azido bridging ligands
	Zhang, Jian-Ying ; Liu, Cai-Ming ; Zhang, De-Qing ; Gao, Song ; Zhu, Dao-Ben
刊名	INORGANIC CHEMISTRY COMMUNICATIONS
	2007-08-01
卷号	10 期号:8 页码:897-901
关键词	Manganese(Ii) Complex Azido Ligand Coordination Polymer Spin Canting Magnetic Property Crystal Structure
ISSN号	1387-7003
DOI	10.1016/j.inoche.2007.04.004
英文摘要	A new one-dimensional (II)) azido-bridged manganese(II) complex, [Mn(dpq)(N-3)2](n) [dpq = dipyrido-(3,2-d:2',3'-f)-quinoxaline] (1), was synthesized and characterized. Crystal structure study reveals that 1 contains a ID manganese(II) chain bridged by alternating double end-to-end (EE) and double end-on (EO) azido ligands. The strong interchain pi-pi stacking interaction extends the structure into a 2D supramolecular array. The analysis of magnetic data indicates that the EO- and EE-azido bridges mediate the ferromagnetic and antiferromagnetic interactions, respectively. Interestingly, complex 1 exhibits a weak ferromagnetic property below 6 K probably due to spin canting. (c) 2007 Elsevier B.V. All rights reserved.
语种	英语
出版者	ELSEVIER SCIENCE BV
WOS记录号	WOS:000248769700013
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/62623]
专题	中国科学院化学研究所
通讯作者	Liu, Cai-Ming
作者单位	1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China 2.Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat & Applicat, Beijing 100871, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100864, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Jian-Ying,Liu, Cai-Ming,Zhang, De-Qing,et al. Spin-canting in a 1D chain Mn(II) complex with alternating double end-on and double end-to-end azido bridging ligands[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2007,10(8):897-901.
APA	Zhang, Jian-Ying,Liu, Cai-Ming,Zhang, De-Qing,Gao, Song,&Zhu, Dao-Ben.(2007).Spin-canting in a 1D chain Mn(II) complex with alternating double end-on and double end-to-end azido bridging ligands.INORGANIC CHEMISTRY COMMUNICATIONS,10(8),897-901.
MLA	Zhang, Jian-Ying,et al."Spin-canting in a 1D chain Mn(II) complex with alternating double end-on and double end-to-end azido bridging ligands".INORGANIC CHEMISTRY COMMUNICATIONS 10.8(2007):897-901.