CORC  > 化学研究所  > 中国科学院化学研究所
Rotamers of m-cresol cation studied by mass-analyzed threshold ionization spectroscopy
Huang, Jiangou; Lin, Jung Lee; Tzeng, Wen Bih
刊名SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
2007-07-01
卷号67期号:3-4页码:989-994
关键词Cresol Rotamer Cation Spectra Multiphoton Ionization Threshold Ionization
ISSN号1386-1425
DOI10.1016/j.saa.2006.09.018
英文摘要We have applied two-color resonant two-photon mass-analyzed threshold ionization technique to record the vibrational spectra of the selected rotamers of m-cresol. The adiabatic ionization energies of cis and trans m-cresol are determined to be 66,933 +/- 5 and 67,084 +/- 5 cm(-1), respectively. Frequencies of the in-plane ring vibrations 6a, 1, and 9b are measured to be 528, 720, 1167 cm(-1) for the cis and 520, 698, and 1153 cm(-1) for the trans m-cresol cation. This indicates that different orientation of the OH group with respect to the CH3 group slightly influences these ring vibrations. (C) 2006 Elsevier B.V. All rights reserved.
语种英语
出版者PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号WOS:000247452400064
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/62525]  
专题中国科学院化学研究所
通讯作者Tzeng, Wen Bih
作者单位1.Acad Sinica, Inst Atom & Mol Sci, Taipei 10617, Taiwan
2.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Huang, Jiangou,Lin, Jung Lee,Tzeng, Wen Bih. Rotamers of m-cresol cation studied by mass-analyzed threshold ionization spectroscopy[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,2007,67(3-4):989-994.
APA Huang, Jiangou,Lin, Jung Lee,&Tzeng, Wen Bih.(2007).Rotamers of m-cresol cation studied by mass-analyzed threshold ionization spectroscopy.SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,67(3-4),989-994.
MLA Huang, Jiangou,et al."Rotamers of m-cresol cation studied by mass-analyzed threshold ionization spectroscopy".SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 67.3-4(2007):989-994.
个性服务
查看访问统计
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。


©版权所有 ©2017 CSpace - Powered by CSpace