Rotamers of m-cresol cation studied by mass-analyzed threshold ionization spectroscopy | |
Huang, Jiangou; Lin, Jung Lee; Tzeng, Wen Bih | |
刊名 | SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
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2007-07-01 | |
卷号 | 67期号:3-4页码:989-994 |
关键词 | Cresol Rotamer Cation Spectra Multiphoton Ionization Threshold Ionization |
ISSN号 | 1386-1425 |
DOI | 10.1016/j.saa.2006.09.018 |
英文摘要 | We have applied two-color resonant two-photon mass-analyzed threshold ionization technique to record the vibrational spectra of the selected rotamers of m-cresol. The adiabatic ionization energies of cis and trans m-cresol are determined to be 66,933 +/- 5 and 67,084 +/- 5 cm(-1), respectively. Frequencies of the in-plane ring vibrations 6a, 1, and 9b are measured to be 528, 720, 1167 cm(-1) for the cis and 520, 698, and 1153 cm(-1) for the trans m-cresol cation. This indicates that different orientation of the OH group with respect to the CH3 group slightly influences these ring vibrations. (C) 2006 Elsevier B.V. All rights reserved. |
语种 | 英语 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
WOS记录号 | WOS:000247452400064 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/62525] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Tzeng, Wen Bih |
作者单位 | 1.Acad Sinica, Inst Atom & Mol Sci, Taipei 10617, Taiwan 2.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Huang, Jiangou,Lin, Jung Lee,Tzeng, Wen Bih. Rotamers of m-cresol cation studied by mass-analyzed threshold ionization spectroscopy[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,2007,67(3-4):989-994. |
APA | Huang, Jiangou,Lin, Jung Lee,&Tzeng, Wen Bih.(2007).Rotamers of m-cresol cation studied by mass-analyzed threshold ionization spectroscopy.SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,67(3-4),989-994. |
MLA | Huang, Jiangou,et al."Rotamers of m-cresol cation studied by mass-analyzed threshold ionization spectroscopy".SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 67.3-4(2007):989-994. |
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