Rate constant for the reaction of ozone with diethyl sulfide

doi:10.1016/j.atmosenv.2007.05.041

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	Rate constant for the reaction of ozone with diethyl sulfide
	Du, Lin 1,2,3; Xu, Yongfu 2; Ge, Maofa 1,2; Jia, Long 4
刊名	ATMOSPHERIC ENVIRONMENT
	2007-11-01
卷号	41 期号:35 页码:7434-7439
关键词	Diethyl Sulfide Ozone Rate Constant
ISSN号	1352-2310
DOI	10.1016/j.atmosenv.2007.05.041
英文摘要	The rate constant for the reaction of diethyl sulfide (DES; C2H5SC2H5) with ozone was determined for the first time, which was (2.77 +/- 0.27) x 10(-19) cm(3) molecule(-1) s(-1) under a room temperature of (289 +/- 1) K. Experiments were conducted under supposedly pseudo-first-order decay conditions, keeping [DES](0) > 50[O-3](0), but having different combinations of [DES](0) and [O-3](0). Cyclohexane was added into the reactor to eliminate the effect of OH radicals. The wall decay of ozone and the role of cyclohexane were also discussed in the present work. (C) 2007 Elsevier Ltd. All rights reserved.
语种	英语
出版者	PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号	WOS:000251829300005
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/62347]
专题	中国科学院化学研究所
通讯作者	Xu, Yongfu
作者单位	1.Chinese Acad Sci, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Inst Atmospher Phys, State Key Lab Atmospher Boundary Layer Phys & Atm, Beijing 100029, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China 4.Beijing Normal Univ, Res Ctr Atmospher Environm, Beijing 100875, Peoples R China
推荐引用方式 GB/T 7714	Du, Lin,Xu, Yongfu,Ge, Maofa,et al. Rate constant for the reaction of ozone with diethyl sulfide[J]. ATMOSPHERIC ENVIRONMENT,2007,41(35):7434-7439.
APA	Du, Lin,Xu, Yongfu,Ge, Maofa,&Jia, Long.(2007).Rate constant for the reaction of ozone with diethyl sulfide.ATMOSPHERIC ENVIRONMENT,41(35),7434-7439.
MLA	Du, Lin,et al."Rate constant for the reaction of ozone with diethyl sulfide".ATMOSPHERIC ENVIRONMENT 41.35(2007):7434-7439.