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Zeolite NaY-mediated oxidation of dyes with H2O2: unique heterogeneous non-transition metal center cleavage of H2O2 under visible light irradiation
Liu LiLi; Ma WanHong; Song WenJing; Chen ChunCheng; Lin Jun; Zhao JinCai; Qian XinHua; Zhang Shibo
刊名SCIENCE IN CHINA SERIES B-CHEMISTRY
2007-12-01
卷号50期号:6页码:770-775
关键词Photooxidation Zeolite Nay Dye Hydrogen Peroxide Visible Light
ISSN号1006-9291
DOI10.1007/s11426-007-0138-1
英文摘要This study investigated the visible-light catalysis mediated by zeolite NaY on the oxidation of dyes with H2O2. The results demonstrated that zeolite NaY acts as a sink for the electron from the photo-excited dye in the heterogeneous catalysis. Furthermore, the electron can effectively activate H2O2 to produce (OH)-O-center dot radical that is a powerful oxidant for the oxidation of dye at room temperature. The effects of the framework topology, Si/Al ratio, and exchangeable cation of the zeolite on the oxidation of various dyes were also shown.
语种英语
出版者SCIENCE CHINA PRESS
WOS记录号WOS:000251412200008
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/62177]  
专题中国科学院化学研究所
通讯作者Ma WanHong
作者单位1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
2.Renmin Univ China, Dept Chem, Beijing 100872, Peoples R China
3.PetroChina Co Ltd, Fushun Petrochem Co, Fushun 113008, Peoples R China
推荐引用方式
GB/T 7714
Liu LiLi,Ma WanHong,Song WenJing,et al. Zeolite NaY-mediated oxidation of dyes with H2O2: unique heterogeneous non-transition metal center cleavage of H2O2 under visible light irradiation[J]. SCIENCE IN CHINA SERIES B-CHEMISTRY,2007,50(6):770-775.
APA Liu LiLi.,Ma WanHong.,Song WenJing.,Chen ChunCheng.,Lin Jun.,...&Zhang Shibo.(2007).Zeolite NaY-mediated oxidation of dyes with H2O2: unique heterogeneous non-transition metal center cleavage of H2O2 under visible light irradiation.SCIENCE IN CHINA SERIES B-CHEMISTRY,50(6),770-775.
MLA Liu LiLi,et al."Zeolite NaY-mediated oxidation of dyes with H2O2: unique heterogeneous non-transition metal center cleavage of H2O2 under visible light irradiation".SCIENCE IN CHINA SERIES B-CHEMISTRY 50.6(2007):770-775.
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