Hydrogen storage properties of [M(Py){Ni(CN)(4)}] (M = Fe, Co, Ni)

doi:10.1016/j.ijhydene.2007.03.006

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	Hydrogen storage properties of [M(Py){Ni(CN)(4)}] (M = Fe, Co, Ni)
	Li, Yan ; Liu, Yang ; Wang, Yuntao ; Leng, Yonghua ; Xie, Lei ; Li, Xingguo
刊名	INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
	2007-10-01
卷号	32 期号:15 页码:3411-3415
关键词	Hydrogen Storage Framework Physisorption
ISSN号	0360-3199
DOI	10.1016/j.ijhydene.2007.03.006
英文摘要	[M(Py){Ni(CN)(4)}] (M = Fe, Co, Ni) frameworks were synthesized by solution method and their hydrogen storage properties were measured using a PCT measuring system. The series of frameworks were found to adsorb twice hydrogen predicted by monolayer adsorption model. Compared with the hydrogen adsorption property of FeFe(CN)(6), this strange phenomenon is elucidated at a molecular level. The pore diameter of Py series is just enough to contain two hydrogen molecules but only one nitrogen molecule is permitted to get in, which leads to the apparent double-layer adsorption. It is concluded that pores with free diameter smaller than 0.42 nm are not favorable for hydrogen storage because no more than one hydrogen molecule can get into them. (C) 2007 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.
语种	英语
出版者	PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号	WOS:000250900700044
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/61789]
专题	中国科学院化学研究所
通讯作者	Li, Xingguo
作者单位	1.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem, Beijing 100871, Peoples R China 2.Peking Univ, Coll Engn, Beijing 100871, Peoples R China
推荐引用方式 GB/T 7714	Li, Yan,Liu, Yang,Wang, Yuntao,et al. Hydrogen storage properties of [M(Py){Ni(CN)(4)}] (M = Fe, Co, Ni)[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2007,32(15):3411-3415.
APA	Li, Yan,Liu, Yang,Wang, Yuntao,Leng, Yonghua,Xie, Lei,&Li, Xingguo.(2007).Hydrogen storage properties of [M(Py){Ni(CN)(4)}] (M = Fe, Co, Ni).INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,32(15),3411-3415.
MLA	Li, Yan,et al."Hydrogen storage properties of [M(Py){Ni(CN)(4)}] (M = Fe, Co, Ni)".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 32.15(2007):3411-3415.