Reaction of CH3 with NO2

doi:10.1360/cjcp2007.20(1).31.6

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	Reaction of CH3 with NO2
	Shi, Cong-yun ; Dong, Feng ; Sun, Shuo ; Zhang, Hao ; Guo, Li ; Feng, Ji-kang ; Kong, Fan-ao
刊名	CHINESE JOURNAL OF CHEMICAL PHYSICS
	2007-02-27
卷号	20 期号:1 页码:31-36
关键词	ch3+no2 Time-resolved Ftir Spectroscopy Quantum Chemical Calculation Reaction Product Reaction Mechanism
ISSN号	1003-7713
DOI	10.1360/cjcp2007.20(1).31.6
英文摘要	The elementary reaction of the CH3 radical with NO2 was investigated by time-resolved FTIR spectroscopy and quantum chemical calculations. The CH3 radical was produced by laser photolysis of CH3Br or CH3I at 248 nm. Vibrationally excited products OH, HNO and CO2 were observed by the time-resolved spectroscopy for the first time. The formation of another product NO was also verified. According to these observations, the product channels leading to CH3O+NO, CH2NO+OH and HNO+H2CO were identified. The channel of CH3O+NO was the major one. The reaction mechanisms of the above channels were studied by quantum chemical calculations at CCSD(T)/6-311++G(df,p)//MP2/6-311G(d,p) level. The calculated results fit with the experimental observations well.
语种	英语
出版者	SCIENCE CHINA PRESS
WOS记录号	WOS:000244804700006
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/61523]
专题	中国科学院化学研究所
通讯作者	Feng, Ji-kang
作者单位	1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China 2.Jilin Univ, Coll Chem, Inst Theoret Chem, Changchun 130023, Peoples R China
推荐引用方式 GB/T 7714	Shi, Cong-yun,Dong, Feng,Sun, Shuo,et al. Reaction of CH3 with NO2[J]. CHINESE JOURNAL OF CHEMICAL PHYSICS,2007,20(1):31-36.
APA	Shi, Cong-yun.,Dong, Feng.,Sun, Shuo.,Zhang, Hao.,Guo, Li.,...&Kong, Fan-ao.(2007).Reaction of CH3 with NO2.CHINESE JOURNAL OF CHEMICAL PHYSICS,20(1),31-36.
MLA	Shi, Cong-yun,et al."Reaction of CH3 with NO2".CHINESE JOURNAL OF CHEMICAL PHYSICS 20.1(2007):31-36.