A new reaction for the generation of carbene from alpha-amino acid and ketone

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	A new reaction for the generation of carbene from alpha-amino acid and ketone
	Zheng Da-Gui 1; Xiao Zhu-Ping 1; Li Yu-Liang 2
刊名	CHINESE JOURNAL OF ORGANIC CHEMISTRY
	2007-12-01
卷号	27 期号:12 页码:1609-1611
关键词	Dl-valine Hexachloroacetone Carbene Azomethine Ylide
ISSN号	0253-2786
英文摘要	2-Phenyl-1-chloro-1-trichloroacetylcyclopropane (3) was obtained from the reaction of styrene with carbene generated by refluxing the mixture of DL-valine and hexachloroacetone in chlorobenzene under an atmosphere of nitrogen. The structure of 3 was characterized by FT-IR, EI-MS and H-1 NMR spectra. The possible reaction mechanism was suggested.
语种	英语
出版者	SCIENCE CHINA PRESS
WOS记录号	WOS:000251996300027
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/61335]
专题	中国科学院化学研究所
通讯作者	Zheng Da-Gui
作者单位	1.Shangrao Normal Coll, Dept Chem, Shangrao 334001, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Zheng Da-Gui,Xiao Zhu-Ping,Li Yu-Liang. A new reaction for the generation of carbene from alpha-amino acid and ketone[J]. CHINESE JOURNAL OF ORGANIC CHEMISTRY,2007,27(12):1609-1611.
APA	Zheng Da-Gui,Xiao Zhu-Ping,&Li Yu-Liang.(2007).A new reaction for the generation of carbene from alpha-amino acid and ketone.CHINESE JOURNAL OF ORGANIC CHEMISTRY,27(12),1609-1611.
MLA	Zheng Da-Gui,et al."A new reaction for the generation of carbene from alpha-amino acid and ketone".CHINESE JOURNAL OF ORGANIC CHEMISTRY 27.12(2007):1609-1611.