2-arylimino-9-phenyl-1,10-phenanthrolinyl-iron, -cobalt and -nickel complexes: Synthesis, characterization and ethylene oligomerization behavior

doi:10.1002/ejic.200700690

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	2-arylimino-9-phenyl-1,10-phenanthrolinyl-iron, -cobalt and -nickel complexes: Synthesis, characterization and ethylene oligomerization behavior
	Jie, Suyun 1,2; Zhang, Shu 1,2; Sun, Wen-Hua1,2
刊名	EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
	2007-12-01
期号	35 页码:5584-5598
关键词	Nitrogen Ligands Late Transition Metals Iron Ethylene Oligomerization
ISSN号	1434-1948
DOI	10.1002/ejic.200700690
英文摘要	A series of 2-imino-9-phenyl-1,10-phenanthrolines 1-6 has been prepared and investigated as new tridentate N3 ligands in coordination with metal chlorides. Their iron(II) (1a-6a), cobalt(II) (1b-6b), and nickel(II) (1c-6c) complexes have been synthesized and characterized by elemental and spectroscopic analysis in conjunction with single-crystal X-ray diffraction studies. Some of the iron complexes show good activities in the selective dimerization of ethylene upon treatment with MAO or MMAO, while the cobalt complexes show higher activities than their iron analogues and lead to the formation of C-6 and C-8 oligomers. The nickel complexes display high catalytic activities toward ethylene oligomerization in the presence of Et2AlCl and an auxiliary ligand (PPh3). ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007).
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000252112600015
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/60803]
专题	中国科学院化学研究所
通讯作者	Sun, Wen-Hua
作者单位	1.Chinese Acad Sci, Key Lab Engn Plast, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Key Lab Engn Plast, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Jie, Suyun,Zhang, Shu,Sun, Wen-Hua. 2-arylimino-9-phenyl-1,10-phenanthrolinyl-iron, -cobalt and -nickel complexes: Synthesis, characterization and ethylene oligomerization behavior[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2007(35):5584-5598.
APA	Jie, Suyun,Zhang, Shu,&Sun, Wen-Hua.(2007).2-arylimino-9-phenyl-1,10-phenanthrolinyl-iron, -cobalt and -nickel complexes: Synthesis, characterization and ethylene oligomerization behavior.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(35),5584-5598.
MLA	Jie, Suyun,et al."2-arylimino-9-phenyl-1,10-phenanthrolinyl-iron, -cobalt and -nickel complexes: Synthesis, characterization and ethylene oligomerization behavior".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .35(2007):5584-5598.