Synthesis and structure of [C2H10N2][B5O8(OH)]: A nonmetal pentaborate with nonlinear optical properties

doi:10.1021/cg0606794

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	Synthesis and structure of [C2H10N2][B5O8(OH)]: A nonmetal pentaborate with nonlinear optical properties
	Yang, Sihai; Li, Guobao; Tian, Shujian; Liao, Fuhui; Lin, Jianhua
刊名	CRYSTAL GROWTH & DESIGN
	2007-07-01
卷号	7 期号:7 页码:1246-1250
ISSN号	1528-7483
DOI	10.1021/cg0606794
英文摘要	A nonmetal pentaborate [C2H10N2][B5O8(OH)] (I) was synthesized by a solvothermal method at 150 degrees C and characterized by elemental analysis, IR, thermogravimetric analysis, and X-ray diffraction. The structure of I was determined by a single-crystal technique. It crystallizes in the monoclinic system with space group Cc, a = 6.7085 (13) angstrom, b = 11.437(2) angstrom, c = 12.530(3) angstrom, and beta = 95.41(3)degrees. Powder second-harmonic generation (SHG) efficiency measurements with Nd:YAG laser (1064 nm) radiation show that [C2H10N2][B5O8(OH)] has a SHG efficiency approximately 1.2 times of that of potassium dihydrogen phosphate (KDP).
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000247678000008
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/60459]
专题	中国科学院化学研究所
通讯作者	Li, Guobao
作者单位	Peking Univ, BNLMS, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
推荐引用方式 GB/T 7714	Yang, Sihai,Li, Guobao,Tian, Shujian,et al. Synthesis and structure of [C2H10N2][B5O8(OH)]: A nonmetal pentaborate with nonlinear optical properties[J]. CRYSTAL GROWTH & DESIGN,2007,7(7):1246-1250.
APA	Yang, Sihai,Li, Guobao,Tian, Shujian,Liao, Fuhui,&Lin, Jianhua.(2007).Synthesis and structure of [C2H10N2][B5O8(OH)]: A nonmetal pentaborate with nonlinear optical properties.CRYSTAL GROWTH & DESIGN,7(7),1246-1250.
MLA	Yang, Sihai,et al."Synthesis and structure of [C2H10N2][B5O8(OH)]: A nonmetal pentaborate with nonlinear optical properties".CRYSTAL GROWTH & DESIGN 7.7(2007):1246-1250.