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Synthesis of optically active polymers bearing amino acid moieties by atom transfer radical polymerization
Feng, Liang; Zhao, Fa Bao; Liu, Zhi Lei; Sun, Jian Ping; Hu, Ji Wen
刊名CHINESE CHEMICAL LETTERS
2007-07-01
卷号18期号:7页码:875-878
关键词Optically Active Polymer Atom Transfer Radical Polymerization Poly[N-methacryloyl L-leucine Methyl Ester]
ISSN号1001-8417
DOI10.1016/j.cclet.2007.05.010
英文摘要We report here an approach toward the synthesis of optically active polyacrylarnide bearing amino acid moieties, poly[N-methacrylOyl L-leucine methyl ester] (PMALM), with controlled average number molecular weight (M-n) and relatively narrow polydispersity index (PDI, M-w/M-n < 1.3) by atom transfer radical polymerization (ATRP) using initiating system methyl 2-bromopropionate/CuBr/tris(2-dimethylaminoethyl) amine. The optical properties of the resulting polymers were evaluated from specific optical rotation value and CD spectra. (C) 2007 Ji Wen Hu. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All fights reserved.
语种英语
出版者CHINESE CHEMICAL SOCIETY
WOS记录号WOS:000248207000032
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/60357]  
专题中国科学院化学研究所
通讯作者Hu, Ji Wen
作者单位Chinese Acad Sci, Inst Chem, Guangzhou 510650, Peoples R China
推荐引用方式
GB/T 7714
Feng, Liang,Zhao, Fa Bao,Liu, Zhi Lei,et al. Synthesis of optically active polymers bearing amino acid moieties by atom transfer radical polymerization[J]. CHINESE CHEMICAL LETTERS,2007,18(7):875-878.
APA Feng, Liang,Zhao, Fa Bao,Liu, Zhi Lei,Sun, Jian Ping,&Hu, Ji Wen.(2007).Synthesis of optically active polymers bearing amino acid moieties by atom transfer radical polymerization.CHINESE CHEMICAL LETTERS,18(7),875-878.
MLA Feng, Liang,et al."Synthesis of optically active polymers bearing amino acid moieties by atom transfer radical polymerization".CHINESE CHEMICAL LETTERS 18.7(2007):875-878.
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