All solid-state comb-like network polymer electrolytes based on poly(methylsiloxane)

doi:10.1016/j.jpowsour.2005.11.019

CORC > 化学研究所 > 中国科学院化学研究所

	All solid-state comb-like network polymer electrolytes based on poly(methylsiloxane)
	Jiang, Hui; Fang, Shibi
刊名	JOURNAL OF POWER SOURCES
	2006-09-13
卷号	159 期号:1 页码:673-678
关键词	All Solid-state Comb-like Polymer Electrolyte Ionic Conductivity Mechanical Property Uv Polymerization
ISSN号	0378-7753
DOI	10.1016/j.jpowsour.2005.11.019
英文摘要	All solid-state comb-like network polymer electrolytes (CNPE) based on poly(methylsiloxane) with pendant PEO chains as internal plasticizing chains (IPC) have been designed and synthesized. Ultraviolet (UV) polymerization method was applied for the curing of CNPEs. Effects of the network structure on the conductive properties and mechanical properties were discussed in details. Ionic conductivity of the prepared CNPE is one order of magnitude larger than those without IPCs, which suggests that the expected drop of conductivity caused by crosslinking has been well compensated by the introduction of IPCs. Maximum conductivity of 1.01 x 10(-4) S cm(-1) and maximum tensile strength of 0.66 MPa were obtained at 30 degrees C. Electrochemical stability and electrolyte/electrodes interfacial stability properties were evaluated by cyclic voltammetry and ac impedance, respectively. (c) 2005 Elsevier B.V. All rights reserved.
语种	英语
出版者	ELSEVIER SCIENCE BV
WOS记录号	WOS:000241012000112
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/59781]
专题	中国科学院化学研究所
通讯作者	Fang, Shibi
作者单位	Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Jiang, Hui,Fang, Shibi. All solid-state comb-like network polymer electrolytes based on poly(methylsiloxane)[J]. JOURNAL OF POWER SOURCES,2006,159(1):673-678.
APA	Jiang, Hui,&Fang, Shibi.(2006).All solid-state comb-like network polymer electrolytes based on poly(methylsiloxane).JOURNAL OF POWER SOURCES,159(1),673-678.
MLA	Jiang, Hui,et al."All solid-state comb-like network polymer electrolytes based on poly(methylsiloxane)".JOURNAL OF POWER SOURCES 159.1(2006):673-678.