Synthesis and crystal structure of an ion-pair supramolecular associate 2,9-diformyl-1,10-phenanthrolinebis-(2,6-dimethylanil)cobalt(II) perchlorate

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	Synthesis and crystal structure of an ion-pair supramolecular associate 2,9-diformyl-1,10-phenanthrolinebis-(2,6-dimethylanil)cobalt(II) perchlorate
	Li Gang ; Jie Su-Yun ; Tang Ning ; Sun Wen-Hua
刊名	CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
	2006
卷号	25 期号:7 页码:861-865
关键词	Cobalt Complex Crystal Structure Hydrogen Bond 1 10-phenanthroline
ISSN号	0254-5861
英文摘要	2,9-Diformyl-1,10-phenanthroline bis(2,6-dimethylanil)cobalt(II) perchlorate was synthesized and demonstrated to be [CoL2] [ClO4](2) by X-ray diffraction analysis. It crystallizes in the monoclinic system, space group C2/c with a = 22.294(4), b = 15.122(3), c = 20.640(4) angstrom, beta = 119.618(4)degrees, V = 6048.9(19) angstrom(3), C63H52Cl2CoN9O9, M-r = 1208.97, F(000) = 2504, D-c = 1.328g/cm(3), Z = 4, mu = 0.436, the final R = 0.0712 and wR = 0.1718 for 1734 observed reflections (I > 2 sigma(I)). In its solid state the helical polymeric chains are supramolecularly associated through intermolecular and inter-ionic hydrogen bonding interactions.
语种	英语
出版者	CHINESE JOURNAL STRUCTURAL CHEMISTRY
WOS记录号	WOS:000239418100019
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/59117]
专题	中国科学院化学研究所
通讯作者	Sun Wen-Hua
作者单位	1.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100080, Peoples R China 2.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
推荐引用方式 GB/T 7714	Li Gang,Jie Su-Yun,Tang Ning,et al. Synthesis and crystal structure of an ion-pair supramolecular associate 2,9-diformyl-1,10-phenanthrolinebis-(2,6-dimethylanil)cobalt(II) perchlorate[J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,2006,25(7):861-865.
APA	Li Gang,Jie Su-Yun,Tang Ning,&Sun Wen-Hua.(2006).Synthesis and crystal structure of an ion-pair supramolecular associate 2,9-diformyl-1,10-phenanthrolinebis-(2,6-dimethylanil)cobalt(II) perchlorate.CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,25(7),861-865.
MLA	Li Gang,et al."Synthesis and crystal structure of an ion-pair supramolecular associate 2,9-diformyl-1,10-phenanthrolinebis-(2,6-dimethylanil)cobalt(II) perchlorate".CHINESE JOURNAL OF STRUCTURAL CHEMISTRY 25.7(2006):861-865.