Solvothermal synthesis, crystal structure and magnetic property of a new dinuclear manganese(II)-azido complex: [Mn(2,2 '-dpa)(N-3)(2)](2) (2,2 '-dpa=2,2 '-dipicolylamine) | |
Liu, CM; Gao, S; Zhang, DQ; Liu, ZL; Zhu, DB | |
刊名 | INORGANICA CHIMICA ACTA
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2005-02-15 | |
卷号 | 358期号:3页码:834-838 |
关键词 | Manganese(Ii) Complexes Azide Complexes Solvothermal Synthesis Crystal Structures Magnetic Properties |
ISSN号 | 0020-1693 |
DOI | 10.1016/j.ica.2004.09.043 |
英文摘要 | A new dinuclear manganese(II)-azido complex: [Mn(2,2'-dpa)(N-3)(2)](2) 1 (2,2'-dpa = 2,2'-dipicolylamine) has been synthesized solvothermally. X-ray crystallography analysis reveals that it consists of two crystallographically independent dimeric manganese moieties; each manganese(II) atom is coordinated by one 2,2'-dipicolylamine, one terminal azido ligand, and double end-on bridging azido ligands, exhibiting a slightly distorted octahedral sphere. There are extensive short contacts among dimeric manganese moieties, which extend the structure into an interesting three-dimensional supramolecular array. Magnetic determination of 1 indicates that dominant ferromagnetic interaction and weak antiferromagnetic interaction, which are ascribed to the end-on azido bridges and the short contacts, respectively, co-exist in this complex. (C) 2004 Elsevier B.V. All rights reserved. |
语种 | 英语 |
出版者 | ELSEVIER SCIENCE SA |
WOS记录号 | WOS:000226259600041 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/57643] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Zhu, DB |
作者单位 | 1.CAS, Ctr Mol Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China 2.Peking Univ, State Key Lab Rare Earth Mat & Applicat, Beijing 100871, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, CM,Gao, S,Zhang, DQ,et al. Solvothermal synthesis, crystal structure and magnetic property of a new dinuclear manganese(II)-azido complex: [Mn(2,2 '-dpa)(N-3)(2)](2) (2,2 '-dpa=2,2 '-dipicolylamine)[J]. INORGANICA CHIMICA ACTA,2005,358(3):834-838. |
APA | Liu, CM,Gao, S,Zhang, DQ,Liu, ZL,&Zhu, DB.(2005).Solvothermal synthesis, crystal structure and magnetic property of a new dinuclear manganese(II)-azido complex: [Mn(2,2 '-dpa)(N-3)(2)](2) (2,2 '-dpa=2,2 '-dipicolylamine).INORGANICA CHIMICA ACTA,358(3),834-838. |
MLA | Liu, CM,et al."Solvothermal synthesis, crystal structure and magnetic property of a new dinuclear manganese(II)-azido complex: [Mn(2,2 '-dpa)(N-3)(2)](2) (2,2 '-dpa=2,2 '-dipicolylamine)".INORGANICA CHIMICA ACTA 358.3(2005):834-838. |
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