Solvothermal synthesis, crystal structure and magnetic property of a new dinuclear manganese(II)-azido complex: [Mn(2,2 '-dpa)(N-3)(2)](2) (2,2 '-dpa=2,2 '-dipicolylamine)

doi:10.1016/j.ica.2004.09.043

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	Solvothermal synthesis, crystal structure and magnetic property of a new dinuclear manganese(II)-azido complex: [Mn(2,2 '-dpa)(N-3)(2)](2) (2,2 '-dpa=2,2 '-dipicolylamine)
	Liu, CM ; Gao, S ; Zhang, DQ ; Liu, ZL ; Zhu, DB
刊名	INORGANICA CHIMICA ACTA
	2005-02-15
卷号	358 期号:3 页码:834-838
关键词	Manganese(Ii) Complexes Azide Complexes Solvothermal Synthesis Crystal Structures Magnetic Properties
ISSN号	0020-1693
DOI	10.1016/j.ica.2004.09.043
英文摘要	A new dinuclear manganese(II)-azido complex: [Mn(2,2'-dpa)(N-3)(2)](2) 1 (2,2'-dpa = 2,2'-dipicolylamine) has been synthesized solvothermally. X-ray crystallography analysis reveals that it consists of two crystallographically independent dimeric manganese moieties; each manganese(II) atom is coordinated by one 2,2'-dipicolylamine, one terminal azido ligand, and double end-on bridging azido ligands, exhibiting a slightly distorted octahedral sphere. There are extensive short contacts among dimeric manganese moieties, which extend the structure into an interesting three-dimensional supramolecular array. Magnetic determination of 1 indicates that dominant ferromagnetic interaction and weak antiferromagnetic interaction, which are ascribed to the end-on azido bridges and the short contacts, respectively, co-exist in this complex. (C) 2004 Elsevier B.V. All rights reserved.
语种	英语
出版者	ELSEVIER SCIENCE SA
WOS记录号	WOS:000226259600041
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/57643]
专题	中国科学院化学研究所
通讯作者	Zhu, DB
作者单位	1.CAS, Ctr Mol Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China 2.Peking Univ, State Key Lab Rare Earth Mat & Applicat, Beijing 100871, Peoples R China
推荐引用方式 GB/T 7714	Liu, CM,Gao, S,Zhang, DQ,et al. Solvothermal synthesis, crystal structure and magnetic property of a new dinuclear manganese(II)-azido complex: [Mn(2,2 '-dpa)(N-3)(2)](2) (2,2 '-dpa=2,2 '-dipicolylamine)[J]. INORGANICA CHIMICA ACTA,2005,358(3):834-838.
APA	Liu, CM,Gao, S,Zhang, DQ,Liu, ZL,&Zhu, DB.(2005).Solvothermal synthesis, crystal structure and magnetic property of a new dinuclear manganese(II)-azido complex: [Mn(2,2 '-dpa)(N-3)(2)](2) (2,2 '-dpa=2,2 '-dipicolylamine).INORGANICA CHIMICA ACTA,358(3),834-838.
MLA	Liu, CM,et al."Solvothermal synthesis, crystal structure and magnetic property of a new dinuclear manganese(II)-azido complex: [Mn(2,2 '-dpa)(N-3)(2)](2) (2,2 '-dpa=2,2 '-dipicolylamine)".INORGANICA CHIMICA ACTA 358.3(2005):834-838.