Supramolecular structures based on bis(2-hydroxy-5-chlorophenyl) sulfide and spirobicromane with bipyridines | |
Zeng, QD; Wu, DX; Wang, C; Ma, HW; Lu, J; Liu, CM; Xu, SD; Li, Y; Bai, CL | |
刊名 | CRYSTAL GROWTH & DESIGN
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2005-09-01 | |
卷号 | 5期号:5页码:1889-1896 |
ISSN号 | 1528-7483 |
DOI | 10.1021/cg0501783 |
英文摘要 | Six new supramolecular structures have been prepared by bis(2-hydroxy-5-chlorophenyl) sulfide (HCS) and/or spirobicromane (SBC) with bipyridine bases 4,4'-bipyridyl (bipy), 1,2-di(4-pyridyl)ethylene (dipy-ete), 1,2-bis(4-pyridyl)ethane (bipy-eta), and 4,4'-dipyridyl N,N'-dioxide (dipy-dox). These molecular complexes are (HCS)(bipy) 1, (HCS)(.)(dipy-ete) 2, (HCS)(.)(bipy-eta) 3, (HCS)-(dipy-dox)4, (SBC)-(dipy-ete) 5, and (SBC)-(dipy-dox)(H2O)-H-. 6, respectively. The crystal structures of 1-6 have been determined by single crystal X-ray diffraction. All of these molecular complexes exhibit supramolecular structures via O-(HN)-N-... or O-(HO)-O-... hydrogen bondings. Both 1 and 2 form interestingly [2 + 2] macrocyclic structures, whose sizes are ca. 12.495(6) angstrom x 5.087(6) angstrom and 14.774(6) angstrom x 5.300(6) angstrom, respectively. Compounds 3 and 5 form one-dimensional zigzag chain structures. Compounds 4 and 6 form two-dimensional double helices. These results demonstrate that by changing the guest molecule, we can obtain different hydrogen-bonded supramolecular structures through different interactions. |
语种 | 英语 |
出版者 | AMER CHEMICAL SOC |
WOS记录号 | WOS:000231767400039 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/57259] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Zeng, QD |
作者单位 | 1.Chinese Acad Sci, Ctr Mol Sci, Inst Chem, Beijing 100080, Peoples R China 2.Natl Ctr Nanosci & Nanotechnol, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Zeng, QD,Wu, DX,Wang, C,et al. Supramolecular structures based on bis(2-hydroxy-5-chlorophenyl) sulfide and spirobicromane with bipyridines[J]. CRYSTAL GROWTH & DESIGN,2005,5(5):1889-1896. |
APA | Zeng, QD.,Wu, DX.,Wang, C.,Ma, HW.,Lu, J.,...&Bai, CL.(2005).Supramolecular structures based on bis(2-hydroxy-5-chlorophenyl) sulfide and spirobicromane with bipyridines.CRYSTAL GROWTH & DESIGN,5(5),1889-1896. |
MLA | Zeng, QD,et al."Supramolecular structures based on bis(2-hydroxy-5-chlorophenyl) sulfide and spirobicromane with bipyridines".CRYSTAL GROWTH & DESIGN 5.5(2005):1889-1896. |
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