Supramolecular structures based on bis(2-hydroxy-5-chlorophenyl) sulfide and spirobicromane with bipyridines

doi:10.1021/cg0501783

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	Supramolecular structures based on bis(2-hydroxy-5-chlorophenyl) sulfide and spirobicromane with bipyridines
	Zeng, QD ; Wu, DX ; Wang, C ; Ma, HW ; Lu, J ; Liu, CM ; Xu, SD ; Li, Y ; Bai, CL
刊名	CRYSTAL GROWTH & DESIGN
	2005-09-01
卷号	5 期号:5 页码:1889-1896
ISSN号	1528-7483
DOI	10.1021/cg0501783
英文摘要	Six new supramolecular structures have been prepared by bis(2-hydroxy-5-chlorophenyl) sulfide (HCS) and/or spirobicromane (SBC) with bipyridine bases 4,4'-bipyridyl (bipy), 1,2-di(4-pyridyl)ethylene (dipy-ete), 1,2-bis(4-pyridyl)ethane (bipy-eta), and 4,4'-dipyridyl N,N'-dioxide (dipy-dox). These molecular complexes are (HCS)(bipy) 1, (HCS)(.)(dipy-ete) 2, (HCS)(.)(bipy-eta) 3, (HCS)-(dipy-dox)4, (SBC)-(dipy-ete) 5, and (SBC)-(dipy-dox)(H2O)-H-. 6, respectively. The crystal structures of 1-6 have been determined by single crystal X-ray diffraction. All of these molecular complexes exhibit supramolecular structures via O-(HN)-N-... or O-(HO)-O-... hydrogen bondings. Both 1 and 2 form interestingly [2 + 2] macrocyclic structures, whose sizes are ca. 12.495(6) angstrom x 5.087(6) angstrom and 14.774(6) angstrom x 5.300(6) angstrom, respectively. Compounds 3 and 5 form one-dimensional zigzag chain structures. Compounds 4 and 6 form two-dimensional double helices. These results demonstrate that by changing the guest molecule, we can obtain different hydrogen-bonded supramolecular structures through different interactions.
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000231767400039
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/57259]
专题	中国科学院化学研究所
通讯作者	Zeng, QD
作者单位	1.Chinese Acad Sci, Ctr Mol Sci, Inst Chem, Beijing 100080, Peoples R China 2.Natl Ctr Nanosci & Nanotechnol, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Zeng, QD,Wu, DX,Wang, C,et al. Supramolecular structures based on bis(2-hydroxy-5-chlorophenyl) sulfide and spirobicromane with bipyridines[J]. CRYSTAL GROWTH & DESIGN,2005,5(5):1889-1896.
APA	Zeng, QD.,Wu, DX.,Wang, C.,Ma, HW.,Lu, J.,...&Bai, CL.(2005).Supramolecular structures based on bis(2-hydroxy-5-chlorophenyl) sulfide and spirobicromane with bipyridines.CRYSTAL GROWTH & DESIGN,5(5),1889-1896.
MLA	Zeng, QD,et al."Supramolecular structures based on bis(2-hydroxy-5-chlorophenyl) sulfide and spirobicromane with bipyridines".CRYSTAL GROWTH & DESIGN 5.5(2005):1889-1896.