Hydrothermal synthesis, crystal structure and magnetic properties of a new 2D layered vanadium oxide complex: [Ni(phen)(H2O)](2)V4O12

doi:10.1080/0095897042000327923

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	Hydrothermal synthesis, crystal structure and magnetic properties of a new 2D layered vanadium oxide complex: [Ni(phen)(H2O)](2)V4O12
	Liu, CM ; Gao, S ; Zhang, DQ ; Zhu, DB
刊名	JOURNAL OF COORDINATION CHEMISTRY
	2005-03-10
卷号	58 期号:4 页码:327-334
关键词	Hydrothermal Synthesis Nickel(Ii) Complex Vanadium Oxide Crystal Structure Magnetic Properties 1 10-phenanthroline
ISSN号	0095-8972
DOI	10.1080/0095897042000327923
英文摘要	A new organic-inorganic hybrid vanadium oxide complex, [Ni(phen)(H2O)](2)V4O12, 1 (phen = 1,10-phenanthroline), has been synthesized using a hydrothermal method and structurally characterized. Complex I exhibits a layered structure in which vanadium oxide chains, {V2O6}(2n-)(n) are linked to [Ni(phen)(H2O)](2+) subunits to form a two-dimensional (2D) topology. Crystals are triclinic, space group P (1) over bar, with a = 7.869(2), b = 9.437(2), 20.992(4) angstrom, alpha = 89.95(3), beta = 89.84(3), gamma = 67.22(3)degrees, V = 1437.3(5)angstrom(3) and Z = 2. Magnetic measurements indicate that 1 exhibits a weak ferromagnetic exchange interaction.
语种	英语
出版者	TAYLOR & FRANCIS LTD
WOS记录号	WOS:000228012300005
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/57217]
专题	中国科学院化学研究所
通讯作者	Liu, CM
作者单位	1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China 2.Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
推荐引用方式 GB/T 7714	Liu, CM,Gao, S,Zhang, DQ,et al. Hydrothermal synthesis, crystal structure and magnetic properties of a new 2D layered vanadium oxide complex: [Ni(phen)(H2O)](2)V4O12[J]. JOURNAL OF COORDINATION CHEMISTRY,2005,58(4):327-334.
APA	Liu, CM,Gao, S,Zhang, DQ,&Zhu, DB.(2005).Hydrothermal synthesis, crystal structure and magnetic properties of a new 2D layered vanadium oxide complex: [Ni(phen)(H2O)](2)V4O12.JOURNAL OF COORDINATION CHEMISTRY,58(4),327-334.
MLA	Liu, CM,et al."Hydrothermal synthesis, crystal structure and magnetic properties of a new 2D layered vanadium oxide complex: [Ni(phen)(H2O)](2)V4O12".JOURNAL OF COORDINATION CHEMISTRY 58.4(2005):327-334.